Metal Organic Frameworks as Heterogeneous Catalysts
Catalysis has always been part of the development of mankind; from the fermentation of alcoholic drinks, through the development of fertilisers in the agricultural revolution and production of bulk chemicals in the 20th Century. Today, society demands improved production routes with greater product output and energy efficiency; the ultimate goal to achieving this would be having all catalytic reactions in concert, effectively functioning like a biological cell.
Metal organic frameworks (MOFs) are a relatively new type of hybrid material. Their crystalline porous structure, built up from organic and inorganic building blocks, presents a vast array of composition, porosity and functionality offering enormous potential in catalytic systems.
This book examines the latest research and discovery in the use of MOFs in catalysis, highlighting the extent to which these materials have been embraced by the community. Beyond presenting a digest of recent research by major players in the field, the book presents the strategies behind recent developments, providing a lasting reference for seasoned researchers and newcomers to the field.
Metal Organic Frameworks as Heterogeneous Catalysts, The Royal Society of Chemistry, 2013.
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CHAPTER 1: Introductionp1-5ByFrancesc X. Llabrés i Xamena;Francesc X. Llabrés i XamenaInstituto de Tecnología Química UPV‐CSICUniversidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos, s/n, 46022Valencia, SpainSearch for other works by this author on:Jorge GasconJorge GasconCatalysis EngineeringTechnical University of Delft, Julianalaan 136, 2628BL Delft, The Netherlands[email protected]Search for other works by this author on:
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CHAPTER 2: Synthesis of MOFsp9-30ByLars‐Hendrik SchillingLars‐Hendrik SchillingSearch for other works by this author on:
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CHAPTER 3: Post‐synthetic Modification of MOFsp31-75ByAndrew D. BurrowsAndrew D. BurrowsSearch for other works by this author on:
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CHAPTER 4: Characterization of MOFs. 1. Combined Vibrational and Electronic Spectroscopiesp76-142ByFrancesca Bonino;Francesca BoninoDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Quarello 15, Università di Torino, 10135 TorinoItalySearch for other works by this author on:Carlo Lamberti;Carlo LambertiDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Quarello 15, Università di Torino, 10135 TorinoItalySearch for other works by this author on:Sachin Chavan;Sachin ChavanDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Quarello 15, Università di Torino, 10135 TorinoItalyinGAP Centre of Research‐based Innovation Department of ChemistryUniversity of Oslo, P.O. Box 1033, N‐0315 OsloNorway[email protected]Search for other works by this author on:Jenny G. Vitillo;Jenny G. VitilloDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Quarello 15, Università di Torino, 10135 TorinoItalySearch for other works by this author on:Silvia Bordiga*Silvia Bordiga*Department of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Quarello 15, Università di Torino, 10135 TorinoItalySearch for other works by this author on:
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CHAPTER 5: Characterization of MOFs. 2. Long and Local Range Order Structural Determination of MOFs by Combining EXAFS and Diffraction Techniquesp143-208ByELISA Borfecchia;ELISA BorfecchiaDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Giuria 7, University of Turin 10125 TorinoItalySearch for other works by this author on:DIEGO Gianolio;DIEGO GianolioDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Giuria 7, University of Turin 10125 TorinoItalyDiamond Light Source LtdHarwell Science and Innovation Campus, Didcot, OX11 0DEUnited Kingdom[email protected]Search for other works by this author on:GIOVANNI Agostini;GIOVANNI AgostiniDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Giuria 7, University of Turin 10125 TorinoItalySearch for other works by this author on:SILVIA Bordiga;SILVIA BordigaDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Giuria 7, University of Turin 10125 TorinoItalySearch for other works by this author on:CARLO LambertiCARLO LambertiDepartment of ChemistryNIS Centre of Excellence and INSTM Reference Center, Via Giuria 7, University of Turin 10125 TorinoItalySearch for other works by this author on:
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CHAPTER 6: Computational Approach to Chemical Reactivity of MOFsp209-234ByEvgeny A. Pidko;Evgeny A. PidkoInorganic Materials Chemistry groupEindhoven University of Technology, P.O. Box 513, 5600 MB EindhovenThe NetherlandsInstitute for Complex Molecular SystemsEindhoven University of Technology, P.O. Box 513, 5600 MB EindhovenThe Netherlands[email protected]Search for other works by this author on:Emiel J. M. HensenEmiel J. M. HensenInorganic Materials Chemistry groupEindhoven University of Technology, P.O. Box 513, 5600 MB EindhovenThe NetherlandsSearch for other works by this author on:
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CHAPTER 7: Strategies for Creating Active Sites in MOFsp237-267ByFrancesc X. Llabrés i Xamena;Francesc X. Llabrés i XamenaInstituto de Tecnología Química UPV‐CSICUniversidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos, s/n, 46022Valencia, Spain[email protected]Search for other works by this author on:Ignacio Luz;Ignacio LuzInstituto de Tecnología Química UPV‐CSICUniversidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos, s/n, 46022Valencia, Spain[email protected]Search for other works by this author on:Francisco G. CirujanoFrancisco G. CirujanoInstituto de Tecnología Química UPV‐CSICUniversidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos, s/n, 46022Valencia, Spain[email protected]Search for other works by this author on:
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CHAPTER 8: Catalysis at the Metallic Nodes of MOFsp268-288ByFrederik Vermoortele;Frederik VermoorteleCentre for Surface Chemistry and CatalysisUniversity of Leuven, Kasteelpark Arenberg 23, box 2461, 3001 LeuvenBelgium[email protected]Search for other works by this author on:Pieterjan Valvekens;Pieterjan ValvekensCentre for Surface Chemistry and CatalysisUniversity of Leuven, Kasteelpark Arenberg 23, box 2461, 3001 LeuvenBelgium[email protected]Search for other works by this author on:Dirk De VosDirk De VosCentre for Surface Chemistry and CatalysisUniversity of Leuven, Kasteelpark Arenberg 23, box 2461, 3001 LeuvenBelgium[email protected]Search for other works by this author on:
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CHAPTER 9: Catalysis at the Organic Ligandsp289-309ByJoseph E. Mondloch;Joseph E. MondlochDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL60208U.S.A.Search for other works by this author on:Omar K. Farha;Omar K. FarhaDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL60208U.S.A.Search for other works by this author on:Joseph T. HuppJoseph T. HuppDepartment of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL60208U.S.A.Argonne National Laboratory, Argonne, IL60439U.S.A.[email protected]; o‐[email protected]; j‐[email protected]Search for other works by this author on:
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CHAPTER 10: MOFs as Nano‐reactorsp310-343ByJorge GasconJorge GasconSearch for other works by this author on:
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CHAPTER 11: Asymmetric Catalysis with Chiral Metal Organic Frameworksp344-364ByJoseph M. Falkowski;Joseph M. FalkowskiDepartment of Chemistry, CB#3290University of North Carolina, Chapel Hill, NC 27599USA[email protected]Search for other works by this author on:Sophie Liu;Sophie LiuDepartment of Chemistry, CB#3290University of North Carolina, Chapel Hill, NC 27599USA[email protected]Search for other works by this author on:Wenbin Lin*Wenbin Lin*Department of Chemistry, CB#3290University of North Carolina, Chapel Hill, NC 27599USA[email protected]Search for other works by this author on:
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CHAPTER 12: Photocatalysis by MOFsp365-383ByHermenegildo García;Hermenegildo GarcíaInstituto de Tecnología Química UPV‐CSICUniversidad Politécnica de Valencia, Consejo Superior de Investigaciones CientíficasSpainSearch for other works by this author on:Belén FerrerBelén FerrerSearch for other works by this author on:
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CHAPTER 13: Catalysis by Covalent Organic Frameworks (COFs)p384-405ByMarcus Rose;Marcus RoseLehrstuhl für Nanostrukturierte KatalysatorenInstitut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, 52074 AachenGermany[email protected]‐aachen.deSearch for other works by this author on:Regina Palkovits*Regina Palkovits*Lehrstuhl für Nanostrukturierte KatalysatorenInstitut für Technische und Makromolekulare Chemie, RWTH Aachen University, Worringerweg 1, 52074 AachenGermany[email protected]‐aachen.deSearch for other works by this author on:
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CHAPTER 14: Towards Future MOF Catalytic Applicationsp406-424ByFrancesc X. Llabrés i Xamena;Francesc X. Llabrés i XamenaInstituto de Tecnología Química UPV‐CSIC, Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Avda. de los Naranjos, s/n, 46022ValenciaSpainSearch for other works by this author on:Jorge GasconJorge GasconCatalysis Engnieering, Technical University of Delft, Julianalaan 136, 2628 BL DelftThe Netherlands[email protected]Search for other works by this author on:
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