CHAPTER 7: Strategies for Creating Active Sites in MOFs

This chapter presents a general overview of the main properties of MOFs that make them very appealing for applications in heterogeneous catalysis. Great efforts have been directed in the last decade to study the potential of MOFs in catalysis. We will now see what is behind this “MOF rush”. Next, we will present some general considerations that should be taken into account when planning the use of MOFs as heterogeneous catalysts, such as stability, recovery and reusability. And finally, we will review the different strategies that can be used to introduce the desired catalytic centers into the MOFs. We will show how it is possible by using these strategies to engineer the material for catalysis, and to fine tune the properties of the MOF to influence the catalytic performance.