CHAPTER 5: Characterization of MOFs. 2. Long and Local Range Order Structural Determination of MOFs by Combining EXAFS and Diffraction Techniques

This chapter provides an elementary introduction to X‐ray and neutron scattering theory, written with a didactic perspective. At the beginning, the scattering process is introduced in a general way and then a differentiation between crystalline samples and amorphous samples is made, leading to the Bragg equation or to the Debye equation and to the Pair Distribution Function (PDF) approach, respectively. Advantages and disadvantages of the use of X‐rays or neutrons for scattering experiments are underlined. The basics of Extended X‐ray Absorption Fine Structure (EXAFS) spectroscopy are also reported. Starting from these basics, five examples have been selected from the recent literature where the concepts described in the first didactic part have been applied to the understanding of the structure of different MOFs materials.