Chapter 3: Supported Metal Catalysts for Green Reactions
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Published:22 Jun 2015
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Special Collection: 2015 ebook collection , ECCC Environmental eBooks 1968-2022 , 2011-2015 physical chemistry subject collectionSeries: Green Chemistry Series
K. Hara, H. Kobayashi, T. Komanoya, S. Huang, M. Pruski, and A. Fukuoka, in Heterogeneous Catalysis for Today's Challenges: Synthesis, Characterization and Applications, ed. B. Trewyn, The Royal Society of Chemistry, 2015, ch. 3, pp. 61-76.
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With the increased cost and rarity of noble metals and with increasing global energy and resource problems, much effort has been put forth toward the development of supported metal catalysts. Many recent publications have reported on extensive applications in bioindustry as well as the utilization of novel catalyst components to exhibit uniquely required performances. This chapter reviews such recent progress in supported metal catalyst with special focus on (i) applications in bioindustry, (ii) the mechanistic aspect in preferential oxidation of carbon monoxide in excess hydrogen (PROX reaction), and (iii) the surface-selective functionalization of mesoporous silica.