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Boron-doped diamond is an ideal material as an electrode for electrochemical and biochemical sensing applications. In this chapter we summarize the fabrication, properties, and applications of all-diamond electrochemical devices. Several devices fabricated in our lab are shown in detail, including all-diamond ultra-microelectrode arrays, nanoelectrode arrays, and atomic force microscope–scanning electrochemical microscope (AFM-SECM) tips.

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