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Polymer Chemistry Series
Thiol‐X Chemistries in Polymer and Materials Science
By
Royal Society of Chemistry
Royal Society of Chemistry
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Edited by
Andrew Lowe;
Andrew Lowe
University of New South Wales, Australia
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Christopher Bowman
Christopher Bowman
University of Colorado at Boulder, USA
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Hardback ISBN:
978-1-84973-660-2
PDF ISBN:
978-1-84973-696-1
Series:
Polymer Chemistry Series
No. of Pages:
336
Publication date:
13 Aug 2013
Book Chapter
CHAPTER 7: Dendritic Polymers from Thiol–Yne Reactions
By
Raphael Barbey
;
Raphael Barbey
Key Centre for Polymers & Colloids, School of Chemistry, Building F11
University of Sydney, NSW 2006
Australia
[email protected]
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Sébastien Perrier
Sébastien Perrier
Key Centre for Polymers & Colloids, School of Chemistry, Building F11
University of Sydney, NSW 2006
Australia
[email protected]
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Published:13 Aug 2013
-
Series: Polymer Chemistry Series
Page range:
151 - 164
Citation
R. Barbey and S. Perrier, in Thiol‐X Chemistries in Polymer and Materials Science, ed. A. Lowe and C. Bowman, The Royal Society of Chemistry, 2013, pp. 151-164.
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We review the use of thiol–yne reaction for the design of branched structures, dendrimers and hyperbranched polymers. In addition to its typical ‘click’ chemistry attributes, the advantages of this reaction include the ability to generate almost perfect branching patterns, the possibility to introduce many more functionalities at each generational step and its tolerance towards chemical functionality, allowing the introduction of a wide range of functional groups into the structures.
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