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From C–H to C–C Bonds: Cross-Dehydrogenative-Coupling
Green Chemistry Series
From C–H to C–C Bonds: Cross-Dehydrogenative-Coupling
Edited by
Chao-Jun Li
Chao-Jun Li
McGill University, Canada
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DOI:
https://doi.org/10.1039/9781782620082
Hardback ISBN:
978-1-84973-797-5
PDF ISBN:
978-1-78262-008-2
EPUB ISBN:
978-1-78262-302-1
Series: Green Chemistry
No. of Pages:
316
Publication date:
19 Aug 2014
Book Chapter

CHAPTER 3: Copper-Catalyzed Cross-Dehydrogenative-Coupling Reactions

By
Xiaojian Zheng
Xiaojian Zheng
Department of Chemistry, Renmin University of China
Beijing
100872
China
[email protected]
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;
Zhiping Li
Zhiping Li
Department of Chemistry, Renmin University of China
Beijing
100872
China
[email protected]
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Doi:
https://doi.org/10.1039/9781782620082-00055
Page range:
55 - 66

Copper-catalyzed cross-dehydrogenative-coupling (CDC) reactions have been developed as one of attractive methodologies in synthetic chemistry. One of the notable features of this type of the transformation is the selective and efficient functionalization of relatively acidic sp3 C–H bonds with a variety of nucleophiles (X–H) to form sp3 C–X bonds. The significant advantage of this protocol is attributed to the excellent catalytic properties of copper catalysts in sp3 C–H bond oxidation. In this chapter, the progress of Cu-catalyzed C–C and C–heteroatom bond formation through CDC reactions is presented.

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