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Catalysis Series
New Trends in Cross-Coupling: Theory and Applications
Edited by
Thomas Colacot
Thomas Colacot
Johnson Matthey, USA
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Hardback ISBN:
978-1-84973-896-5
PDF ISBN:
978-1-78262-025-9
EPUB ISBN:
978-1-78262-309-0
Series:
Catalysis Series
No. of Pages:
912
Published online:
13 Oct 2014
Published in print:
27 Oct 2014
Book Chapter
CHAPTER 5: Ancillary Ligand Design in the Development of Palladium Catalysts for Challenging Selective Monoarylation Reactions
By
Mark Stradiotto
Mark Stradiotto
Department of Chemistry, Dalhousie University
6274 Coburg Road, P.O. Box 15000, Halifax
Nova Scotia
Canada
B3H 4R2
[email protected]
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Published:13 Oct 2014
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Series: Catalysis Series
Page range:
228 - 253
Citation
M. Stradiotto, in New Trends in Cross-Coupling: Theory and Applications, ed. T. Colacot, The Royal Society of Chemistry, 2014, pp. 228-253.
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This chapter documents how the challenge of achieving monoarylation selectivity in palladium-catalyzed Buchwald–Hartwig amination and ketone α-arylation chemistry has been addressed in recent years through the design and/or implementation of sterically demanding phosphine ancillary ligands. Particular attention is given to documenting advances leading to the first reports of the selective monoarylation of ammonia, hydrazine and acetone as representative challenging reaction partners, given the broad synthetic potential of these novel transformations in chemical synthesis.
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