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Catalysis Series
N-Heterocyclic Carbenes
Edited by
Silvia Diez-Gonzalez
Silvia Diez-Gonzalez
Imperial College London, UK
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Hardback ISBN:
978-1-84973-042-6
PDF ISBN:
978-1-84973-216-1
Special Collection:
2010 ebook collection
,
2010 ebook collection
,
2000-2010 organic chemistry subject collection
,
2010 organic chemistry subject collection
Series:
Catalysis Series
No. of Pages:
468
Publication date:
26 Nov 2010
A newer edition is now available:
Latest edition
Book Chapter
Chapter 12: Oxidation Reactions with NHC–Metal Complexes
By
Susanne M. Podhajsky
;
Susanne M. Podhajsky
Department of Chemistry
University of Utah, 315 South 1400 East
Salt Lake City
Utah 84112
USA
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Matthew S. Sigman
Matthew S. Sigman
Department of Chemistry
University of Utah, 315 South 1400 East
Salt Lake City
Utah 84112
USA
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Published:26 Nov 2010
-
Special Collection: 2010 ebook collection , 2010 ebook collection , 2000-2010 organic chemistry subject collection , 2010 organic chemistry subject collectionSeries: Catalysis Series
Page range:
345 - 365
Citation
S. M. Podhajsky and M. S. Sigman, in N-Heterocyclic Carbenes, ed. S. Diez-Gonzalez, The Royal Society of Chemistry, 2010, ch. 12, pp. 345-365.
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An overview of oxidative reactions promoted by N-heterocyclic carbene (NHC) metal complexes is presented. Rather than attempting to provide a comprehensive review, key systems and recent developments are laid out, with special attention given to mechanistic aspects. Specifically, O2 activation by metal carbene complexes is covered, followed by alcohol oxidation, Wacker-type reactions and oxidative cleavage of alkenes, and alkane as well as arene oxidations proceeding via C–H activation.
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