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Catalysis Series
N-Heterocyclic Carbenes
Edited by
Silvia Diez-Gonzalez
Silvia Diez-Gonzalez
Imperial College London, UK
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Hardback ISBN:
978-1-84973-042-6
PDF ISBN:
978-1-84973-216-1
Special Collection:
2010 ebook collection
,
2010 ebook collection
,
2000-2010 organic chemistry subject collection
,
2010 organic chemistry subject collection
Series:
Catalysis Series
No. of Pages:
468
Publication date:
26 Nov 2010
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Latest edition
Book Chapter
Chapter 13: Reduction Reactions with NHC-bearing Complexes
By
Bekir Çetinkaya
Bekir Çetinkaya
Ege University, Department of Chemistry, 35100, Bornova
Izmir
Turkey
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Published:26 Nov 2010
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Special Collection: 2010 ebook collection , 2010 ebook collection , 2000-2010 organic chemistry subject collection , 2010 organic chemistry subject collectionSeries: Catalysis Series
Page range:
366 - 398
Citation
B. Çetinkaya, in N-Heterocyclic Carbenes, ed. S. Diez-Gonzalez, The Royal Society of Chemistry, 2010, ch. 13, pp. 366-398.
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This Chapter summaries the studies conducted on the reduction of multiple-bonded organic compounds in the presence of NHC–metal complexes as homogeneous catalysts. The following reactions have been examined: hydrogenation, transfer hydrogenation, hydrosilylation and hydroboration. Reports of the application of hydrosilylation and hydroboration in the synthesis of complex organic molecules and via subsequent cleavage of Si−C or B−C bonds are also discussed.
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