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In this chapter, the papers devoted to NMR application to study synthetic polymers over a period from June 2013 through May 2014 have been reviewed. It includes analysis of primary structure of polymers such as tacticity, regioregularity, end group, sequence distribution (Section 2), application of imaging, diffusion and solid-state NMR techniques to characterize the synthetic macromolecules (Sections 3 and 4). Finally in Section 5, papers devoted to dynamics of the synthetic macromolecules have been surveyed.

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