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SPR Organometallic Chemistry
Organometallic Chemistry: Volume 41
Edited by
Nathan J Patmore;
Nathan J Patmore
University of Huddersfield, UK
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Paul Elliott
Paul Elliott
University of Huddersfield, UK
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Volume
41
Hardback ISBN:
978-1-78262-416-5
PDF ISBN:
978-1-78262-692-3
EPUB ISBN:
978-1-78801-220-1
Special Collection:
2017 ebook collection
No. of Pages:
156
Published online:
25 Jul 2017
Published in print:
31 Jul 2017
Book Chapter
The diiron centre: Fe2(CO)9 and friends1
By
Graeme Hogarth
Graeme Hogarth
Department of Chemistry, King's College London
Britannia House
7 Trinity Street
London
SE1 1DB
UK
[email protected]
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Published:25 Jul 2017
-
Special Collection: 2017 ebook collection
Page range:
48 - 92
Citation
G. Hogarth, in Organometallic Chemistry: Volume 41, ed. I. Fairlamb, J. M. Lynam, N. J. Patmore, and P. Elliott, The Royal Society of Chemistry, 2017, vol. 41, pp. 48-92.
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From the discovery of Fe2(CO)9 in 1905 to the intensive post-millennium study of dithiolate-bridged diiron complexes as biomimics of the active site of [FeFe]-hydrogenases, over the past century the diiron centre has been the most studied of binuclear systems. In this chapter we will focus on the synthesis, structure, bonding and reactivity of Fe2(CO)9, and derivatives based on the replacement or removal of one or more of the bridging carbonyl ligands.
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