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SPR Organometallic Chemistry
Organometallic Chemistry: Volume 41
Edited by
Nathan J Patmore;
Nathan J Patmore
University of Huddersfield, UK
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Paul Elliott
Paul Elliott
University of Huddersfield, UK
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Volume
41
Hardback ISBN:
978-1-78262-416-5
PDF ISBN:
978-1-78262-692-3
EPUB ISBN:
978-1-78801-220-1
Special Collection:
2017 ebook collection
No. of Pages:
156
Published online:
25 Jul 2017
Published in print:
31 Jul 2017
Book Chapter
Silylamides: towards a half-century of stabilising remarkable f-element chemistry
By
David P. Mills
David P. Mills
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-
Published:25 Jul 2017
-
Special Collection: 2017 ebook collection
Page range:
123 - 156
Citation
C. A. P. Goodwin and D. P. Mills, in Organometallic Chemistry: Volume 41, ed. I. Fairlamb, J. M. Lynam, N. J. Patmore, and P. Elliott, The Royal Society of Chemistry, 2017, vol. 41, pp. 123-156.
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This review highlights some of the outstanding contributions to f-element chemistry that have been supported by monodentate silylamide ligands over the past 45 years, since Bradley reported the first 3-coordinate lanthanide (Ln) complexes, [Ln(N″)3] (N″={N(SiMe3)2}) in 1972. As well as providing a historical perspective, this review presents a plethora of monodentate silylamide f-element complexes with significant geometries, bonding motifs, physical properties and reactivity profiles.
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