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This chapter covers the most relevant literature related to tervalent phosphorus acid derivatives, published between January 2011 and December 2013. Some relevant concepts regarding the main synthetic routes to halogenophosphorus compounds, phosphorus esters (phosphinite, phosphonite and phosphites) and phosphorus amides (aminophosphines, phosphoramidites and diamidophosphites) are reported. Also a critical discussion, with an emphasis on their catalytic applications, is briefly assessed.

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