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The very recent developments of novel photoinitiators and photoinitiating systems in photoinduced radical and cationic polymerization reactions are reviewed. The use of mild irradiation conditions in the blue-to-red wavelength range (household halogen lamps, LEDs, fluorescent bulbs, sunlight; reactions under air) is particularly outlined. New opportunities in applications requiring such experimental conditions in sunlight curing, photoredox initiated polymerizations or in situ incorporation of nanoparticles in a photopolymerizable matrix are described.

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