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Catalysis Series
Proton-Coupled Electron Transfer: A Carrefour of Chemical Reactivity Traditions
Edited by
Sebastiao Formosinho;
Sebastiao Formosinho
University of Coimbra, Portugal
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Monica Barroso
Monica Barroso
Imperial College London, UK
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Hardback ISBN:
978-1-84973-141-6
PDF ISBN:
978-1-84973-316-8
EPUB ISBN:
978-1-78262-449-3
Special Collection:
2011 ebook collection
,
2011 ebook collection
,
2011-2015 physical chemistry subject collection
Series:
Catalysis Series
No. of Pages:
157
Published online:
07 Dec 2011
Published in print:
06 Dec 2011
Book Chapter
Chapter 4: Metal Ion-Coupled and Proton-Coupled Electron Transfer in Catalytic Reduction of Dioxygen
By
Shunichi Fukuzumi
;
Shunichi Fukuzumi
Department of Material and Life Science
Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871
Japan
Department of Bioinspired Science
Ewha Womans University, Seoul 120-
750
Korea
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Hiroaki Kotani
Hiroaki Kotani
Department of Material and Life Science
Graduate School of Engineering, Osaka University, ALCA, Japan Science and Technology Agency (JST), Suita, Osaka 565-0871
Japan
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-
Published:06 Dec 2011
-
Special Collection: 2011 ebook collection , 2011 ebook collection , 2011-2015 physical chemistry subject collectionSeries: Catalysis Series
Page range:
89 - 125
Citation
S. Fukuzumi and H. Kotani, in Proton-Coupled Electron Transfer: A Carrefour of Chemical Reactivity Traditions, ed. S. Formosinho and M. Barroso, The Royal Society of Chemistry, 2011, ch. 4, pp. 89-125.
Download citation file:
Metal ion-coupled and proton-coupled electron-transfer processes are described for one-electron, two-electron, and four-electron reduction of dioxygen by one-electron reductants, such as ferrocene derivatives, as well as by two-electron reductants, such as NADH analogs with metal complexes. The catalytic mechanism of the four-electron reduction of dioxygen as functional models of cytochrome c oxidases has been clarified based on detailed kinetic study and the detection of intermediates.
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