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This report summarises the literature reported in 2010 on the photophysical properties of metal complexes and their polynuclear supramolecular assemblies. The transition metal species considered here have been largely studied because of their optical properties, in particular luminescence. The complexes are from the following metal centres: d6 Ru(II), Os(II), Ir(III), d8 Pt(II) and Rh(III), and Pd(II), and some mention is given of lanthanide (Ln) complexes.

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