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This chapter focuses on compounds with chalcogen to B bonds and reviews the literature published over the period 1990 to year‐end 2011. The review is not comprehensive, but includes all important advances in the field. A significant section of the review examines polyhedral boron hydride cluster species, with the remaining sections covering the themes of review articles, heterocycles, chalcogenoborates, and miscellaneous compounds. The review cites 239 articles.

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