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Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium, Volume 2Check Access
Edited by
Francesco Devillanova;
Francesco Devillanova
University of Cagliari, Italy
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Wolf-Walther Du Mont;
Wolf-Walther Du Mont
Der Technischen Universitat, Germany
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Francesco Devillanova;
Francesco Devillanova
University of Cagliari, Italy
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Wolf-Walther Du Mont
Wolf-Walther Du Mont
Der Technischen Universitat, Germany
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Volume
2
Hardback ISBN:
978-1-84973-624-4
PDF ISBN:
978-1-84973-746-3
No. of Pages:
475
Publication date:
25 Jul 2013
Book Chapter
CHAPTER 10.1: Metal–Sulfur Clusters as the Model for the Active Sites of Metalloenzymes Check Access
By
Yasushi Mizobe
;
Yasushi Mizobe
Institute of Industrial Science, The University of Tokyo, Komaba, Meguro‐ku, Tokyo 153‐8505
Japan
[email protected]‐tokyo.ac.jp
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Hidetake Seino
Hidetake Seino
Institute of Industrial Science, The University of Tokyo, Komaba, Meguro‐ku, Tokyo 153‐8505
Japan
[email protected]‐tokyo.ac.jp
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Published:25 Jul 2013
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Page range:
7 - 24
Citation
Y. Mizobe and H. Seino, in Handbook of Chalcogen Chemistry: New Perspectives in Sulfur, Selenium and Tellurium, Volume 2, ed. F. Devillanova, W. Du Mont, F. Devillanova, and W. Du Mont, The Royal Society of Chemistry, 2nd edn, 2013, vol. 2, pp. 7-24.
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Detailed structures have been clarified for a number of metal–sulfur clusters present at the active sites of metalloenzymes. This chapter describes recent advances in the synthesis of structural models for these clusters, especially focusing on those contained in nitrogenase, FeMo‐cofactor and P‐cluster. The chemistry of synthetic metal–sulfur clusters aiming the functional models for the metalloenzymes is also summarized.
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