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Nanoscience & Nanotechnology Series
Nanostructured Catalysts: Selective Oxidations
By
Royal Society of Chemistry
Royal Society of Chemistry
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Edited by
Christian Hess;
Christian Hess
Eduard-Zintl-Institut für Anorganische Chemie und Physikalische Chemie, Germany
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Robert Schlögl
Robert Schlögl
Fritz Haber Institute of the Max Planck Society, Germany
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Hardback ISBN:
978-0-85404-186-2
PDF ISBN:
978-1-84755-987-6
Special Collection:
2011 ebook collection
,
2011 ebook collection
,
2011-2015 physical chemistry subject collection
No. of Pages:
452
Published online:
22 Jul 2011
Published in print:
09 Aug 2011
Book Chapter
Chapter 15: Characteristics of Selective Oxidation Reactions
By
Robert Schlögl
;
Robert Schlögl
Fritz-Haber-Institut der Max-Planck-Gesellschaft
Abteilung Anorganische Chemie, Faradayweg 4-6
14195
Berlin
Germany
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Christian Hess
Christian Hess
Technische Universität Darmstadt, Eduard-Zintl-Institut für Anorganische und Physikalische Chemie
Petersenstr.
20
64287
Darmstadt
Germany
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-
Published:22 Jul 2011
-
Special Collection: 2011 ebook collection , 2011 ebook collection , 2011-2015 physical chemistry subject collection
Page range:
355 - 397
Citation
R. Schlögl and C. Hess, in Nanostructured Catalysts: Selective Oxidations, ed. C. Hess and R. Schlögl, The Royal Society of Chemistry, 2011, ch. 15, pp. 355-397.
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In this chapter the current state of concepts in selective oxidation reactions is discussed by examining the functions of supported active sites in a redox catalyst of the VxOy type. As model reactions the conversion of propane into its olefin propene and into its oxidation product acrylic acid are considered. The discussion is based on a set of chemical equations giving the minimum of molecular transformations in correct stoichiometric relations for the atoms and formal charges needed to achieve the desired reaction.
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