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Green Chemistry Series
Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 1
Edited by
Michael North;
Michael North
Chair of Green Chemistry, University of York, UK
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Michael North
Michael North
Chair of Green Chemistry, University of York, UK
Search for other works by this author on:
Hardback ISBN:
978-1-78262-640-4
PDF ISBN:
978-1-78262-209-3
EPUB ISBN:
978-1-78262-752-4
Special Collection:
2015 ebook collection
,
ECCC Environmental eBooks 1968-2022
,
2011-2015 physical chemistry subject collection
Series:
Green Chemistry Series
No. of Pages:
379
Publication date:
16 Nov 2015
Book Chapter
Chapter 6: Prolinamides as Asymmetric Organocatalysts
By
Rafael Pedrosa
;
Rafael Pedrosa
Departamento de Química Orgánica and Instituto CINQUIMA, Facultad de Ciencias, Universidad de Valladolid. Paseo de Belén 7
47011-Valladolid
Spain
[email protected]
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José M. Andrés
José M. Andrés
Departamento de Química Orgánica and Instituto CINQUIMA, Facultad de Ciencias, Universidad de Valladolid. Paseo de Belén 7
47011-Valladolid
Spain
[email protected]
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-
Published:16 Nov 2015
-
Special Collection: 2015 ebook collection , ECCC Environmental eBooks 1968-2022 , 2011-2015 physical chemistry subject collectionSeries: Green Chemistry Series
Page range:
120 - 139
Citation
R. Pedrosa and J. M. Andrés, in Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 1, ed. M. North and M. North, The Royal Society of Chemistry, 2015, ch. 6, pp. 120-139.
Download citation file:
Prolinamides are valuable organocatalysts for enantioselective transformations that occur by activation of the nucleophile by enamine formation. Different substituents can be appended on the nitrogen atom of the carboxamide, which allow for the modulation of the catalytic properties. In that way, the acidity, the hydrogen donor properties, the hydrophobicity, or the chiral environment can be modified, in a few steps, starting from easily available proline.
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