Asymmetric Autocatalysis: The Soai Reaction
Asymmetric autocatalysis is a reaction in which chiral compound acts as a chiral catalyst for its own production. The process is a catalytic automultiplication of the chiral compound leading to an end product with a high enantiomeric excess. It has advantages over non-autocatalytic reactions because the amount of catalyst increases and no loss or deterioration of the catalyst is observed. Additionally, because the catalyst and product have the same structure, the separation of product from the catalyst is not necessary.
Asymmetric Autocatalysis provides a comprehensive introduction to the topic of autocatalysis and an in-depth review of the current state of the research. Edited by a team including Professor Kenso Soai, who first described these types of reaction, and written by experts from around the world this book is a great resource for anyone with an interest in organic synthesis, catalysis and chirality.
Asymmetric Autocatalysis: The Soai Reaction, The Royal Society of Chemistry, 2022.
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Chapter 1: Asymmetric Autocatalysis: The Soai Reaction, an Overviewp1-32ByKenso Soai;Kenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo162-8601Japan[email protected]Research Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo162-0041JapanSearch for other works by this author on:Tsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo162-8601Japan[email protected]Search for other works by this author on:Arimasa MatsumotoArimasa MatsumotoDepartment of Chemistry, Nara Women's UniversityKita-Uoya Nishi-machiNara630-8506JapanSearch for other works by this author on:
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Chapter 2: Asymmetric Autocatalysis Initiated by Enantioenriched Chiral Organic Compounds: The Link Between Circularly Polarized Light and Nearly Enantiopure Organic Compoundsp33-42ByTsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601Japan[email protected]Search for other works by this author on:Arimasa Matsumoto;Arimasa MatsumotoDepartment of Chemistry, Biology, and Environmental Science, Nara Women's UniversityKita-Uoya Nishi-machiNara 630-8506JapanSearch for other works by this author on:Kenso SoaiKenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601Japan[email protected]Research Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo 162-0041JapanSearch for other works by this author on:
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Chapter 3: Asymmetric Autocatalysis Triggered by the Chirality of Minerals, Organic Crystals, and Surfacesp43-64ByArimasa Matsumoto;Arimasa MatsumotoDepartment of Chemistry, Biology, and Environmental Science, Nara Women's UniversityKita-Uoya Nishi-machiNara 630-8506Japan[email protected]Search for other works by this author on:Tsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601JapanSearch for other works by this author on:Kenso SoaiKenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601JapanResearch Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo 162-0041JapanSearch for other works by this author on:
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Chapter 4: Absolute Asymmetric Synthesis in the Soai Reactionp65-74ByKenso Soai;Kenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo162-8601Japan[email protected]Research Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo162-0041JapanSearch for other works by this author on:Tsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo162-8601Japan[email protected]Search for other works by this author on:Arimasa MatsumotoArimasa MatsumotoDepartment of Chemistry, Nara Women's UniversityKita-Uoya Nishi-machiNara630-8506JapanSearch for other works by this author on:
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Chapter 5: Isotope Chirality and Cosmochemistry1p75-96ByBéla Barabás;Béla BarabásDepartment of Mathematics, University of Technology and EconomicsMűegyetem rkp. 3(H-ép.)H-1111 BudapestHungarySearch for other works by this author on:Robert Kurdi;Robert KurdiInstitute of Environmental Engineering, University of PannoniaEgyetem u. 10.H-8200 VeszprémHungarySearch for other works by this author on:Marco Maioli;Marco MaioliDepartment of Mathematics, University of Modena and Reggio EmiliaVia Campi 213/BI-41125 ModenaItalySearch for other works by this author on:Gyula PályiGyula PályiDepartment of Life Sciences, University of Modena and Reggio EmiliaVia Campi 103I-41125 ModenaItaly[email protected]Search for other works by this author on:
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Chapter 6: Reaction Mechanism in the Study of Amplifying Asymmetric Autocatalysisp97-128ByJohn M. BrownJohn M. BrownSearch for other works by this author on:
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Chapter 7: Spontaneous Emergence of Chirality in Autocatalytic Cycle Models of the Soai Reactionp129-155ByThomas Buhse;Thomas BuhseCentro de Investigaciones Químicas-IICBA, Universidad Autónoma del Estado de Morelos62209 CuernavacaMorelosMexico[email protected]Search for other works by this author on:María E. Noble-Terán;María E. Noble-TeránCentro de Investigaciones Químicas-IICBA, Universidad Autónoma del Estado de Morelos62209 CuernavacaMorelosMexico[email protected]Search for other works by this author on:David Hochberg;David HochbergDepartment of Molecular Evolution, Centro de Astrobiología (CSIC-INTA)28850 Torrejón de ArdozMadridSpainSearch for other works by this author on:Josep M. Ribó;Josep M. RibóDepartment of Organic and Inorganic Chemistry, Institute of Cosmos Science (IEEC-UB), University of Barcelona08028 BarcelonaCataloniaSpainSearch for other works by this author on:Jean-claude MicheauJean-claude MicheauLaboratoire des IMRCP, UMR au CNRS No. 5623, Université Paul SabatierF-31062 ToulouseFranceSearch for other works by this author on:
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Chapter 8: Mechanism of the Soai Reaction – DFT and Kinetic Computations of the Catalytic Cyclep156-178ByIlya D. Gridnev;Ilya D. GridnevN. D. Zelinsky Institute of Organic ChemistryLeninsky Prospekt 47Moscow 119991Russian Federation[email protected]Department of Chemistry, M. V. Lomonosov Moscow State UniversityLeninskie Gory, Moscow 119991Russian FederationSearch for other works by this author on:Andrey Kh. Vorobiev;Andrey Kh. VorobievDepartment of Chemistry, M. V. Lomonosov Moscow State UniversityLeninskie Gory, Moscow 119991Russian FederationSearch for other works by this author on:Alexey V. BogdanovAlexey V. BogdanovDepartment of Chemistry, M. V. Lomonosov Moscow State UniversityLeninskie Gory, Moscow 119991Russian FederationSearch for other works by this author on:
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Chapter 9: Stochastic Modeling of Asymmetric Autocatalysis in the Soai Reactionp179-198ByGábor LenteGábor LenteSearch for other works by this author on:
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Chapter 10: Demystifying the Soai Reaction1p199-238BySoumitra V. Athavale;Soumitra V. AthavaleRoger Adams Laboratory, Department of Chemistry, University of IllinoisUrbanaIllinois61801USA[email protected]Search for other works by this author on:Scott E. DenmarkScott E. DenmarkRoger Adams Laboratory, Department of Chemistry, University of IllinoisUrbanaIllinois61801USA[email protected]Search for other works by this author on:
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Chapter 11: Elucidation of Soai's Asymmetric Autocatalysisp239-272ByOliver TrappOliver TrappDepartment of Chemistry, Ludwig-Maximilians-University MunichButenandtstr. 5-1381377 MunichGermany[email protected]Search for other works by this author on:
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Chapter 12: Structure Analysis of Asymmetric Autocatalysis by X-ray Crystallography and Circular Dichroism Spectroscopyp273-288ByArimasa Matsumoto;Arimasa MatsumotoDepartment of Chemistry, Biology, and Environmental Science, Nara Women's UniversityKita-Uoya Nishi-machiNara 630-8506Japan[email protected]Search for other works by this author on:Tsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601JapanSearch for other works by this author on:Kenso SoaiKenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601JapanResearch Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo 162-0041JapanSearch for other works by this author on:
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Chapter 13: Symmetry Breaking in a Heterogenous Phase: Intriguing Intermediates and Side-products During Asymmetric Amplificationp289-316ByGiuseppe RotunnoGiuseppe RotunnoSearch for other works by this author on:
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Chapter 14: Unusual Aspects of Asymmetric Induction and Amplification Observed in the Soai Reactionp317-338ByTsuneomi Kawasaki;Tsuneomi KawasakiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601Japan[email protected]Search for other works by this author on:Arimasa Matsumoto;Arimasa MatsumotoDepartment of Chemistry, Biology, and Environmental Science, Nara Women's UniversityKita-Uoya Nishi-machiNara 630-8506JapanSearch for other works by this author on:Kenso SoaiKenso SoaiDepartment of Applied Chemistry, Tokyo University of ScienceKagurazakaShinjuku-kuTokyo 162-8601Japan[email protected]Research Organization for Nano & Life Innovation, Waseda UniversityWasedatsurumaki-choShinjuku-kuTokyo 162-0041JapanSearch for other works by this author on:
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