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Catalysis Series
Asymmetric Autocatalysis: The Soai Reaction
Edited by
Tsuneomi Kawasaki;
Tsuneomi Kawasaki
Tokyo University of Science, Japan
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Arimasa Matsumoto
Arimasa Matsumoto
Nara Women's University, Japan
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Hardback ISBN:
978-1-83916-261-9
PDF ISBN:
978-1-83916-627-3
EPUB ISBN:
978-1-83916-628-0
Special Collection:
2022 ebook collection
Series:
Catalysis Series
No. of Pages:
338
Publication date:
28 Oct 2022
Book Chapter
Chapter 8: Mechanism of the Soai Reaction – DFT and Kinetic Computations of the Catalytic Cycle
By
Ilya D. Gridnev
;
Ilya D. Gridnev
N. D. Zelinsky Institute of Organic Chemistry
Leninsky Prospekt 47
Moscow 119991
Russian Federation
[email protected]Department of Chemistry, M. V. Lomonosov Moscow State University
Leninskie Gory, Moscow 119991
Russian Federation
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Andrey Kh. Vorobiev
;
Andrey Kh. Vorobiev
Department of Chemistry, M. V. Lomonosov Moscow State University
Leninskie Gory, Moscow 119991
Russian Federation
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Alexey V. Bogdanov
Alexey V. Bogdanov
Department of Chemistry, M. V. Lomonosov Moscow State University
Leninskie Gory, Moscow 119991
Russian Federation
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Published:28 Oct 2022
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Special Collection: 2022 ebook collectionSeries: Catalysis Series
Page range:
156 - 178
Citation
I. D. Gridnev, A. K. Vorobiev, and A. V. Bogdanov, in Asymmetric Autocatalysis: The Soai Reaction, ed. K. Soai, T. Kawasaki, and A. Matsumoto, The Royal Society of Chemistry, 2022, ch. 8, pp. 156-178.
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This chapter surveys the results of quantum chemical calculations and kinetic measurements of the Soai reaction presented in the literature. Two computed mechanisms are compared. Contradictions and weaknesses of available kinetic data, as well as the lack of reliable experimental results are illuminated. Possible ways to overcome this shortage are discussed.
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