Organophosphorus Chemistry: Volume 51
Pentacoordinated and hexacoordinated compounds
Published:05 Sep 2022
Special Collection: 2022 ebook collection
Romana Pajkert, Gerd-Volker Röschenthaler, 2022. "Pentacoordinated and hexacoordinated compounds", Organophosphorus Chemistry: Volume 51, Lee J Higham, David W Allen, John C Tebby
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The chemistry of penta- and hexa-coordinated compounds continues to expand in its breadth and application. Regarding this, the synthesis, properties and structural investigations of novel cage-phosphoranes, spiro-phosphoranes, fluorophosphoranes and spiro-oxaphosphetanes have been briefly discussed. Pentacoordinated phosphoranes have also been postulated as intermediates in the synthesis of dibenzophospholes, the carbofluorination of alkynes, Wittig-type reactions and also organocatalytic Mitsunobu reactions. Moreover, studies of novel hexacoordinated fluorinated phosphorus(v) compounds have been also evaluated.