Chapter 8: Synthesis and Applications of Organophosphorus Compounds with a PSe Group
Published:15 Feb 2023
Y. Maekawa and T. Murai, in Chalcogen Chemistry: Fundamentals and Applications, ed. V. Lippolis, C. Santi, E. J. Lenardão, and A. L. Braga, The Royal Society of Chemistry, 2023, ch. 8, pp. 187-224.
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This chapter describes the synthesis and applications of four-coordinate pentavalent organophosphorus compounds with a PSe group, including: (i) the addition reaction of secondary phosphine selenides; (ii) Woollins’ reagent as a selenating agent and its derivatizations to the compounds containing phosphorus and selenium atoms; (iii) chiral phosphoroamidites as Lewis base catalysts; and (iv) PSe compounds with a binaphthyl group as a chiral transfer reagent.