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Chalcogen Chemistry: Fundamentals and Applications
Edited by
Vito Lippolis;
Vito Lippolis
Complesso Universitario di Monserrato, Italy
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Eder J. Lenardão;
Eder J. Lenardão
Universidade Federal de Pelota, Brazil
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Antonio L. Braga
Antonio L. Braga
Universidade Federal de Santa Catarina, Brazil
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Hardback ISBN:
978-1-83916-422-4
PDF ISBN:
978-1-83916-738-6
EPUB ISBN:
978-1-83916-739-3
Special Collection:
2023 ebook collection
No. of Pages:
728
Publication date:
15 Feb 2023
Book Chapter
Chapter 8: Synthesis and Applications of Organophosphorus Compounds with a PSe Group
By
Yuuki Maekawa
;
Yuuki Maekawa
Department of Chemistry and Biomolecular Science, Faculty of Engineering
Gifu University, Yanagido
Gifu 501-1193
Japan
mtoshi@gifu-u.ac.jp
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Toshiaki Murai
Toshiaki Murai
Department of Chemistry and Biomolecular Science, Faculty of Engineering
Gifu University, Yanagido
Gifu 501-1193
Japan
mtoshi@gifu-u.ac.jp
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Published:15 Feb 2023
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Special Collection: 2023 ebook collection
Page range:
187 - 224
Citation
Y. Maekawa and T. Murai, in Chalcogen Chemistry: Fundamentals and Applications, ed. V. Lippolis, C. Santi, E. J. Lenardão, and A. L. Braga, The Royal Society of Chemistry, 2023, ch. 8, pp. 187-224.
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This chapter describes the synthesis and applications of four-coordinate pentavalent organophosphorus compounds with a PSe group, including: (i) the addition reaction of secondary phosphine selenides; (ii) Woollins’ reagent as a selenating agent and its derivatizations to the compounds containing phosphorus and selenium atoms; (iii) chiral phosphoroamidites as Lewis base catalysts; and (iv) PSe compounds with a binaphthyl group as a chiral transfer reagent.
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