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This chapter provides readers with an insight into how to extract valuable materials and energy from municipal solid waste (MSW) via microwave-assisted pyrolysis. The chapter begins with a brief overview of municipal solid waste composition and management followed by a description of the microwave-assisted pyrolysis process, mechanisms involved in microwave heating, and advantages of microwave heating over conventional heating. Two typical cases of microwave-assisted pyrolysis, namely, plastic and biomass conversion, are introduced. Finally, the importance of further research and development is highlighted for reference.

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