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The combined applications of solid acid and solid base catalysis with microwave activation are reviewed. The chapter is divided into three main parts: (i) a brief survey of solid acid and solid base catalysts, such as metal oxides, clays, acidic and basic zeolites, ion-exchange resins, etc. and the application of microwave irradiation in environmentally benign processes, and synthetic applications using (ii) solid acid and (iii) solid base catalysts.

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