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The collection of photochromic systems demonstrated here gives an illustrative overview over recent progress in the concepts and development of molecular photoswitches. These are represented by indigoids (ITI, ITOs, PIOs), dihydropyrenes, nature-inspired 5-membered heterocyclic switches, and hemipiperazines, as well as systems based on novel concepts of electrocyclic photoswitching and radical-involved mechanisms.

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