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Specialist Periodical Reports
Photochemistry: Volume 51
Edited by
Stefano Crespi;
Stefano Crespi
University of Groningen, The Netherlands
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Stefano Protti
Stefano Protti
University of Pavia, Italy
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Hardback ISBN:
978-1-83767-215-8
PDF ISBN:
978-1-83767-230-1
EPUB ISBN:
978-1-83767-231-8
Special Collection:
2023 ebook collection
SPR:
SPR - Photochemistry
No. of Pages:
614
Publication date:
20 Dec 2023
Book Chapter
Photocatalytic enantioselective radical transformation enabled by radical–polar crossover
By
Yue-Die Zhu
;
Yue-Die Zhu
Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
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Pu-Sheng Wang
Pu-Sheng Wang
Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
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Published:20 Dec 2023
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Special Collection: 2023 ebook collectionSPR: SPR - Photochemistry
Page range:
455 - 466
Citation
Y. Zhu and P. Wang, in Photochemistry
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Asymmetric transformation of radicals has always been recognized as a highly challenging issue, compared with the well-developed enantioinduction methods in traditional polar/ionic chemistry. Enantioselective radical polar crossover (RPC) reactions have recently emerged as valuable and powerful tools to assemble molecular complexity that would be impossible using either a radical or polar approach alone. This chapter summarizes the recent and synthetically important stereoselective RPC transformations by merging photoredox catalysis.
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