Flexible Metal–Organic Frameworks: Structural Design, Synthesis and Properties
Flexible metal–organic frameworks (MOFs) are a unique class of porous materials that feature stimuli-responsive flexible structures and dynamic structural transformation behaviours. Exhibiting structural changes in response to physical or chemical stimuli creates related functions that can be developed for practical applications.
The specific components and architectures of flexible MOFs are key to their unique properties, so understanding their chemistry is of critical importance for more targeted construction and functional research.
This book provides an accessible overview of the historical background of the chemistry of flexible MOFs and its features; in particular, design and synthesis, dynamic structure analysis, flexibility, function and theoretical treatment, and interpretation of the mechanisms as well as its applications.
It gives readers a fundamental understanding of this chemistry and will be of great help to young researchers, as well as those already familiar with conventional porous materials in creating new materials.
Flexible Metal–Organic Frameworks: Structural Design, Synthesis and Properties, Royal Society of Chemistry, 2024.
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Chapter 1: Structure, Design and Synthesisp1-61ByAamod V. Desai;Aamod V. DesaiaDepartment of Chemistry, Indian Institute of Science Education and Research (IISER), Pune 411008, IndiabEaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews KY16 9ST, UKSearch for other works by this author on:Yong-Sheng Wei;Yong-Sheng WeicInstitute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, JapanSearch for other works by this author on:Sujit K. Ghosh;Sujit K. GhoshaDepartment of Chemistry, Indian Institute of Science Education and Research (IISER), Pune 411008, IndiadCentre for Water Research (CWR), Indian Institute of Science Education and Research (IISER), Pune 411008, IndiaSearch for other works by this author on:Satoshi HorikeSatoshi HorikecInstitute for Integrated Cell-Material Sciences, Institute for Advanced Study, Kyoto University, Yoshida-Honmachi, Sakyo-ku, Kyoto 606-8501, JapaneDepartment of Chemistry, Graduate School of Science, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, JapanfDepartment of Materials Science and Engineering, School of Molecular Science and Engineering, Vidyasirimedhi Institute of Science and Technology, Rayong, 21210, ThailandSearch for other works by this author on:
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Chapter 2: Flexible Properties: Adsorptive Storage and Separationp62-144ByXue-Wen Zhang;Xue-Wen ZhangaMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou 510275, ChinaSearch for other works by this author on:Zi-Ming Ye;Zi-Ming YeaMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou 510275, ChinaSearch for other works by this author on:Jie-Peng ZhangJie-Peng ZhangaMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou 510275, ChinaSearch for other works by this author on:
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Chapter 3: The Dynamic View: Multiscale Characterisation Techniques for Flexible Frameworksp145-230ByV. Bon;V. BonaChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, TU Dresden, 01062 Dresden, GermanySearch for other works by this author on:K. Roztocki;K. RoztockibFaculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznań, PolandcCenter for Advanced Technologies, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, 61-614 Poznań, PolandSearch for other works by this author on:P. Iacomi;P. IacomidICGM University of Montpellier, CNRS ENSCM, F-34095 Montpellier, FranceSearch for other works by this author on:C. L. Hobday;C. L. HobdayeSchool of Chemistry and Centre for Science at Extreme Conditions, The University of Edinburgh, King’s Buildings, David Brewster Road, Edinburgh, EH9 3FJ, Scotland, UKSearch for other works by this author on:I. Senkovska;I. SenkovskaaChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, TU Dresden, 01062 Dresden, GermanySearch for other works by this author on:A. Pöppl;A. PöpplfFelix-Bloch-Institut für Festkörperphysik, Fakultät für Physik und Geowissenschaften, Universität Leipzig, Linnéstraße 5, 04103 Leipzig, GermanySearch for other works by this author on:E. Brunner;E. BrunnergChair of Bioanalytical Chemistry, Faculty of Chemistry and Food Chemistry TU Dresden, 01062 Dresden, GermanySearch for other works by this author on:S. KaskelS. KaskelaChair of Inorganic Chemistry I, Faculty of Chemistry and Food Chemistry, TU Dresden, 01062 Dresden, GermanySearch for other works by this author on:
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Chapter 4: Theoretical Understanding and Insights on Flexible Metal–Organic Frameworksp231-303ByL. Vanduyfhuys;L. VanduyfhuysaCenter for Molecular Modeling, Ghent University, Technologiepark 46, Zwijnaarde B-9052, BelgiumSearch for other works by this author on:M. Wahiduzzaman;M. WahiduzzamanbICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier 34095, FranceSearch for other works by this author on:S. M. J. Rogge;S. M. J. RoggeaCenter for Molecular Modeling, Ghent University, Technologiepark 46, Zwijnaarde B-9052, BelgiumSearch for other works by this author on:G. Maurin;G. MaurinbICGM, Univ. Montpellier, CNRS, ENSCM, Montpellier 34095, FranceSearch for other works by this author on:V. van SpeybroeckV. van SpeybroeckaCenter for Molecular Modeling, Ghent University, Technologiepark 46, Zwijnaarde B-9052, BelgiumSearch for other works by this author on:
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Chapter 5: New Dimensions of Flexible MOFs: Toward Complex Systems and Devicesp304-367ByRui-Biao Lin;Rui-Biao LinaMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou, 510275, ChinaSearch for other works by this author on:Xiao-Ming Chen;Xiao-Ming ChenaMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, GBRCE for Functional Molecular Engineering, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou, 510275, ChinaSearch for other works by this author on:Susumu Kitagawa;Susumu KitagawabInstitute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, 606-8501, JapanSearch for other works by this author on:Banglin ChenBanglin ChencFujian Provincial Key Laboratory of Polymer Materials, College of Chemistry & Materials Science, Fujian Normal University, Fuzhou, 350007, ChinaSearch for other works by this author on:
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