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Coordination Chemistry Discovery
Redox-based Catalytic Chemistry of Transition Metal Complexes
Edited by
Takahiko Kojima
Takahiko Kojima
University of Tsukuba, Japan
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Volume
2
Hardback ISBN:
978-1-83767-469-5
PDF ISBN:
978-1-83767-648-4
EPUB ISBN:
978-1-83767-647-7
Special Collection:
2024 eBook Collection
Series:
Coordination Chemistry Discovery
No. of Pages:
394
Publication date:
20 Dec 2024
Book Chapter
Chapter 15: Catalytic Reactions by Metal Clusters
By
Kazushi Mashima
;
Kazushi Mashima
aGraduate School of Pharmaceuticals, Osaka University, Japan [email protected]
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Hayato Tsurugi
;
Hayato Tsurugi
bGraduate School of Engineering, Osaka University, Japan [email protected]
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Haruki Nagae
Haruki Nagae
cNational Institute of Advanced Industrial Science and Technology (AIST), Japan
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Published:20 Dec 2024
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Special Collection: 2024 eBook CollectionSeries: Coordination Chemistry Discovery
Page range:
268 - 294
Citation
K. Mashima, H. Tsurugi, and H. Nagae, in Redox-based Catalytic Chemistry of Transition Metal Complexes, ed. T. Kojima, Royal Society of Chemistry, 2024, vol. 2, ch. 15, pp. 268-294.
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Multiple metal cluster complexes supported by alkoxide or carboxylate ligands as well as oxo, imido or nitride, and hydride serve as unique and intrinsic catalysts with peculiar reactivity and selectivity based on the concerted catalytic performance of two or more proximately arranged homo or hetero metals. This chapter highlights the catalytic reactions of these clusters for Lewis acid–base reactions, oxidation reactions, radical reactions, etc.
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