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Electrochemical corrosion monitoring stands at the forefront of strategies employed to safeguard metallic structures from the pervasive threat of corrosion. This chapter delves into the intricate world of electrochemical corrosion monitoring techniques, exploring their principles, applications, and advancements. Electrochemical processes underlying corrosion are elucidated using potentiodynamic polarization, electrochemical impedance spectroscopy, cyclic voltammetry, and pitting and general corrosion monitoring methods. The nuanced insights provided by these techniques into corrosion mechanisms are detailed, facilitating a comprehensive understanding of material degradation. Challenges and prospects in the field are addressed, underscoring ongoing efforts to develop and extend the applicability of electrochemical corrosion monitoring to various materials and conditions. By providing detailed insights into these electrochemical techniques, this chapter assist researchers, engineers, and practitioners striving to reduce the deleterious effects of corrosion and ensure the longevity of metallic structures.

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