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This chapter attempts to summarize the major part of existing information from the past 20 years dedicated to the application of gold-based catalysts in the water gas shift reaction. It is organized in five-year periods in which the most relevant aspects concerning the gold-based materials are described. Within the groups, the achievements are organized around the nature of the support, in a wish to underline the evolution of the materials and at the same time to emphasize the extreme importance of the supports for the good performance of the catalytic systems.

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