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Catalysis Series
Heterogeneous Gold Catalysts and Catalysis
Hardback ISBN:
978-1-84973-917-7
PDF ISBN:
978-1-78262-164-5
EPUB ISBN:
978-1-78262-304-5
Series:
Catalysis Series
No. of Pages:
634
Published online:
20 Aug 2014
Published in print:
08 Sep 2014
Book Chapter
CHAPTER 8: Advances in Catalytic Reactions by Gold-based Catalysts Through the Radical Chain Mechanism
By
Xue-Jing Yang
;
Xue-Jing Yang
East China University of Science and Technology, State Key Laboratory of Chemical Engineering
130 Meilong Road
Shanghai
200237
PR China
[email protected].
Search for other works by this author on:
Like Ouyang
;
Like Ouyang
East China University of Science and Technology, State Key Laboratory of Chemical Engineering
130 Meilong Road
Shanghai
200237
PR China
[email protected].
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Jing Xu
;
Jing Xu
East China University of Science and Technology, State Key Laboratory of Chemical Engineering
130 Meilong Road
Shanghai
200237
PR China
[email protected].
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Yi-Fan Han
Yi-Fan Han
East China University of Science and Technology, State Key Laboratory of Chemical Engineering
130 Meilong Road
Shanghai
200237
PR China
[email protected].
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Published:20 Aug 2014
-
Series: Catalysis Series
Page range:
229 - 287
Citation
X. Yang, L. Ouyang, J. Xu, and Y. Han, in Heterogeneous Gold Catalysts and Catalysis, ed. Z. Ma and S. Dai, The Royal Society of Chemistry, 2014, pp. 229-287.
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Unlike the published literature, the chapter focuses on recent developments in our understanding of the radicals involved catalytic reactions on heterogeneous gold-based catalysts. This chapter is composed of four parts: (1) selective oxidation of alkanes; (2) selective oxidation of alkenes; (3) selective oxidation of alcohols and aldehydes; and (4) Fenton-like reaction and photocatalytic oxidation. The role of gold in the decomposition of hydrogen peroxide is analysed and the mechanism for the production of hydroxyl radicals (•OH) is envisaged.
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