Skip Nav Destination
Polymer Chemistry Series
Nitroxide Mediated Polymerization: From Fundamentals to Applications in Materials Science
Edited by
Didier Gigmes
Didier Gigmes
Aix-Marseille University, France
Search for other works by this author on:
Hardback ISBN:
978-1-78262-061-7
PDF ISBN:
978-1-78262-263-5
EPUB ISBN:
978-1-78262-796-8
Special Collection:
2015 ebook collection
Series:
Polymer Chemistry Series
No. of Pages:
512
Published online:
08 Dec 2015
Published in print:
11 Dec 2015
Book Chapter
Chapter 2: Kinetic Aspects of Nitroxide Mediated Polymerization
By
Elena G. Bagryanskaya
;
Elena G. Bagryanskaya
N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RAS
Pr. Lavrentjeva 9
630090 Novosibirsk
Russia
Novosibirsk State University
Pirogova 2
630090 Novosibirsk
Russia
Search for other works by this author on:
Sylvain R. A. Marque
Sylvain R. A. Marque
Aix Marseille Université, CNRS, ICR UMR 7273
13397 Marseille cedex 20
France
[email protected][email protected]
Search for other works by this author on:
-
Published:08 Dec 2015
-
Special Collection: 2015 ebook collectionSeries: Polymer Chemistry Series
Page range:
45 - 113
Citation
E. G. Bagryanskaya and S. R. A. Marque, in Nitroxide Mediated Polymerization: From Fundamentals to Applications in Materials Science, ed. D. Gigmes, The Royal Society of Chemistry, 2015, ch. 2, pp. 45-113.
Download citation file:
The peculiarities of key reactions in nitroxide-mediated polymerization and the main factors that determine their rate constants are discussed. The process and kinetics of nitroxide-mediated polymerization is determined by the rate constants of: (i) the decomposition of alkoxyamines and macroalkoxyamines, (ii) the recombination of nitroxides and alkyl radicals and (iii) the side reactions. The methods and techniques for the determination of these rate constants are also discussed.
You do not currently have access to this chapter, but see below options to check access via your institution or sign in to purchase.
Digital access
$64.60
