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Catalysis Series
Asymmetric Functionalization of C–H Bonds
Edited by
Shu-Li You
Shu-Li You
Chinese Academy of Sciences, China
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Hardback ISBN:
978-1-78262-102-7
PDF ISBN:
978-1-78262-196-6
EPUB ISBN:
978-1-78262-654-1
Series:
Catalysis Series
No. of Pages:
432
Publication date:
30 Jul 2015
Book Chapter
CHAPTER 8: Asymmetric Hydroacylation Reactions
By
Qing-Long Xu
;
Qing-Long Xu
Jiangsu Key Laboratory of Drug Discovery for Metabolic Disease and Center of Drug Discovery, China Pharmaceutical University
24 Tongjia Xiang
Nanjing 210009
China
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Shu-Li You
Shu-Li You
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
345 Lingling Lu
Shanghai 200032
China
slyou@sioc.ac.cn
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Published:30 Jul 2015
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Series: Catalysis Series
Citation
Q. Xu and S. You, in Asymmetric Functionalization of C–H Bonds, ed. S. You, The Royal Society of Chemistry, 2015, pp. 358-383.
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The hydroacylation reaction is an attractive subfield of C–H bond functionalization reactions, realizing direct transformation of the acyl C–H bond of aldehydes. The asymmetric hydroacylation reactions, either intra- or intermolecular, have been developed in recent years with various catalytic systems, among which the Rh-based catalysts hold a central position. In this chapter, we present recent developments of the asymmetric hydroacylation of alkenes, allenes, alkynes, and ketones.
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