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Catalysis Series
Asymmetric Functionalization of C–H Bonds
Edited by
Shu-Li You
Shu-Li You
Chinese Academy of Sciences, China
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Hardback ISBN:
978-1-78262-102-7
PDF ISBN:
978-1-78262-196-6
EPUB ISBN:
978-1-78262-654-1
Series:
Catalysis Series
No. of Pages:
432
Publication date:
30 Jul 2015
Book Chapter
CHAPTER 9: Asymmetric Hydrovinylation Reactions
By
Qing-Long Xu
;
Qing-Long Xu
Jiangsu Key Laboratory of Drug Discovery for Metabolic Disease and Center of Drug Discovery, China Pharmaceutical University
24 Tongjia Xiang
Nanjing 210009
China
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Shu-Li You
Shu-Li You
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences
345 Lingling Lu
Shanghai 200032
China
slyou@sioc.ac.cn
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Published:30 Jul 2015
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Series: Catalysis Series
Citation
Q. Xu and S. You, in Asymmetric Functionalization of C–H Bonds, ed. S. You, The Royal Society of Chemistry, 2015, pp. 384-404.
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Among the transition metal-catalyzed asymmetric carbon–carbon bond-forming processes, the asymmetric hydrovinylation reaction, which can be defined as the formal addition of ethylene across the double bond of an olefin, is one of the most efficient reactions in organic synthesis. In the field of hydrovinylation reactions, the biggest challenge is how to improve the selectivity and achieve enantioselective reactions. In this chapter, we aim to give the whole picture of the current asymmetric hydrovinylation reactions catalyzed by transition metal systems.
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