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Catalysis Series
N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools
Edited by
Silvia Diez-Gonzalez
Silvia Diez-Gonzalez
Imperial College London, UK
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Hardback ISBN:
978-1-78262-423-3
PDF ISBN:
978-1-78262-681-7
EPUB ISBN:
978-1-78262-903-0
Special Collection:
2016 ebook collection
Series:
Catalysis Series
No. of Pages:
636
Published online:
04 Nov 2016
Published in print:
08 Nov 2016
Book Chapter
CHAPTER 6: Rare Earth Metal Complexes with N-Heterocyclic Carbenes
By
Fritz E. Kühn
Fritz E. Kühn
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Published:04 Nov 2016
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Special Collection: 2016 ebook collectionSeries: Catalysis Series
Page range:
238 - 267
Citation
J. Rieb, L. Schaper, E. Tosh, W. A. Herrmann, and F. E. Kühn, in N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, ed. S. Diez-Gonzalez, The Royal Society of Chemistry, 2nd edn, 2016, pp. 238-267.
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This chapter provides a general overview on the structural variety of rare earth metal complexes supported by N-heterocyclic carbenes. The synthetic procedures and strategies are discussed in some detail. The general trends with respect to structures and bonding situations are elucidated, based on experimental and theoretical studies. This chapter also covers tentative reactivity studies and possible catalytic applications of these metal complexes.
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