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Catalysis Series
N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools
Edited by
Silvia Diez-Gonzalez
Silvia Diez-Gonzalez
Imperial College London, UK
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Hardback ISBN:
978-1-78262-423-3
PDF ISBN:
978-1-78262-681-7
EPUB ISBN:
978-1-78262-903-0
Special Collection:
2016 ebook collection
Series:
Catalysis Series
No. of Pages:
636
Published online:
04 Nov 2016
Published in print:
08 Nov 2016
Book Chapter
CHAPTER 8: NHC–Cobalt, –Rhodium, and –Iridium Complexes in Catalysis
By
Vincent César
;
Vincent César
Laboratoire de Chimie de Coordination du CNRS
205 route de Narbonne
31077 Toulouse Cedex 4
France
[email protected]
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Lutz H. Gade
;
Lutz H. Gade
Anorganisch-Chemisches Institut, Universität Heidelberg
Im Neuenheimer Feld 270
69120 Heidelberg
Germany
[email protected]
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Stéphane Bellemin-Laponnaz
Stéphane Bellemin-Laponnaz
Institut de Physique et Chimie des Matériaux de Strasbourg, CNRS-Université de Strasbourg
23 rue du Loess
67034 Strasbourg Cedex 2
France
[email protected]
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Published:04 Nov 2016
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Special Collection: 2016 ebook collectionSeries: Catalysis Series
Page range:
302 - 335
Citation
V. César, L. H. Gade, and S. Bellemin-Laponnaz, in N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, ed. S. Diez-Gonzalez, The Royal Society of Chemistry, 2nd edn, 2016, pp. 302-335.
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Since the mid-1990s, N-heterocyclic carbenes (NHCs) have proved to be a versatile class of ancillary ligands in catalysis. The NHC chemistry of Group 9 metals (Co, Rh, Ir) is one of the most developed areas in this field and is the subject of this chapter. The chapter covers the most relevant catalytic applications, along with stoichiometric model reactions, except for catalytic oxidation and reduction reactions which are covered in Chapters 12 and 13, respectively.
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