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Catalysis Series
N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools
Edited by
Silvia Diez-Gonzalez
Silvia Diez-Gonzalez
Imperial College London, UK
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Hardback ISBN:
978-1-78262-423-3
PDF ISBN:
978-1-78262-681-7
EPUB ISBN:
978-1-78262-903-0
Special Collection:
2016 ebook collection
Series:
Catalysis Series
No. of Pages:
636
Published online:
04 Nov 2016
Published in print:
08 Nov 2016
Book Chapter
CHAPTER 13: Reduction Reactions with NHC-Bearing Complexes
By
Bekir Çetinkaya
Bekir Çetinkaya
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Published:04 Nov 2016
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Special Collection: 2016 ebook collectionSeries: Catalysis Series
Page range:
484 - 533
Citation
S. Gülcemal and B. Çetinkaya, in N-Heterocyclic Carbenes: From Laboratory Curiosities to Efficient Synthetic Tools, ed. S. Diez-Gonzalez, The Royal Society of Chemistry, 2nd edn, 2016, pp. 484-533.
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This chapter summarizes the studies conducted on the reduction of unsaturated organic compounds in the presence of NHC–metal complexes as homogeneous catalysts. The following reactions have been examined: hydrogenation, transfer hydrogenation, hydrosilylation and hydroboration. Reports of the application of hydrosilylation and hydroboration in the synthesis of complex organic molecules and via subsequent cleavage of Si–C or B–C bonds are also discussed.
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