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Green Chemistry Series
Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 2
Edited by
Michael North;
Michael North
Chair of Green Chemistry, University of York, UK
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Michael North
Michael North
Chair of Green Chemistry, University of York, UK
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Hardback ISBN:
978-1-78262-641-1
PDF ISBN:
978-1-78262-643-5
EPUB ISBN:
978-1-78262-753-1
Special Collection:
2015 ebook collection
,
ECCC Environmental eBooks 1968-2022
,
2011-2015 physical chemistry subject collection
Series:
Green Chemistry
No. of Pages:
459
Publication date:
16 Nov 2015
Book Chapter
Chapter 17: Binaphthyl-derived Cyclic Amines and Their Salts as Asymmetric Organocatalysts
By
Taichi Kano
;
Taichi Kano
Department of Chemistry, Graduate School of Science, Kyoto University
Sakyo, Kyoto 606-8502
Japan
kano@kuchem.kyoto-u.ac.jpmaruoka@kuchem.kyoto-u.ac.jp
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Keiji Maruoka
Keiji Maruoka
Department of Chemistry, Graduate School of Science, Kyoto University
Sakyo, Kyoto 606-8502
Japan
kano@kuchem.kyoto-u.ac.jpmaruoka@kuchem.kyoto-u.ac.jp
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-
Published:16 Nov 2015
-
Special Collection: 2015 ebook collection , ECCC Environmental eBooks 1968-2022 , 2011-2015 physical chemistry subject collectionSeries: Green Chemistry
Citation
T. Kano and K. Maruoka, in Sustainable Catalysis: Without Metals or Other Endangered Elements, Part 2, ed. M. North and M. North, The Royal Society of Chemistry, 2015, ch. 17, pp. 135-163.
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A series of binaphthyl-based secondary amines and quaternary ammonium salts have been designed for asymmetric enamine and phase-transfer catalysis. These chiral organocatalysts have been successfully applied to several asymmetric reactions and exhibited unique reactivity and selectivity in comparison with organocatalysts derived from naturally occurring amino acids and Cinchona alkaloids.
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