Chapter 5: Homogeneous Titanium-based Catalysts for Nonasymmetric Transformations
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Published:16 Nov 2015
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Special Collection: 2015 ebook collection , ECCC Environmental eBooks 1968-2022 , 2011-2015 physical chemistry subject collectionSeries: Green Chemistry
J. A. Castro-Osma and G. Durá, in Sustainable Catalysis: With Non-endangered Metals, Part 1, ed. M. North and M. North, The Royal Society of Chemistry, 2015, ch. 5, pp. 103-115.
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This chapter covers developments on titanium-containing complexes as homogeneous catalysts for nonasymmetric transformations since 2010. Titanium complexes show high catalytic activity and broad applications in organic synthesis. The chapter gives an overview of titanium-catalysed processes in organic synthesis and is organised by the catalytic process and subdivided by type of reaction. The focus will be on reactions involving carbon–carbon (crosscoupling, hydroaminoalkylation, Barbier-type and oligomerisation reactions) and carbon–heteroatom (hydroamination, cyclisation, hetero-Diels–Alder and multicomponent reactions) bond-forming reactions, reduction and oxidation reactions.
