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Green Chemistry Series
Sustainable Catalysis: With Non-endangered Metals, Part 1
Edited by
Michael North;
Michael North
Chair of Green Chemistry, University of York, UK
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Michael North
Michael North
Chair of Green Chemistry, University of York, UK
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Hardback ISBN:
978-1-78262-638-1
PDF ISBN:
978-1-78262-211-6
EPUB ISBN:
978-1-78262-754-8
Special Collection:
2015 ebook collection
,
ECCC Environmental eBooks 1968-2022
,
2011-2015 physical chemistry subject collection
Series:
Green Chemistry
No. of Pages:
506
Publication date:
16 Nov 2015
Book Chapter
Chapter 9: Vanadium- and Niobium-catalysed Enantioselective Reactions
By
Hiroaki Sasai
;
Hiroaki Sasai
The Institute of Scientific and Industrial Research (ISIR), Osaka University
Mihogaoka, Ibaraki-shi
Osaka 567-0047
Japan
[email protected][email protected]
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Shinobu Takizawa
Shinobu Takizawa
The Institute of Scientific and Industrial Research (ISIR), Osaka University
Mihogaoka, Ibaraki-shi
Osaka 567-0047
Japan
[email protected][email protected]
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-
Published:16 Nov 2015
-
Special Collection: 2015 ebook collection , ECCC Environmental eBooks 1968-2022 , 2011-2015 physical chemistry subject collectionSeries: Green Chemistry
Page range:
216 - 249
Citation
H. Sasai and S. Takizawa, in Sustainable Catalysis: With Non-endangered Metals, Part 1, ed. M. North and M. North, The Royal Society of Chemistry, 2015, ch. 9, pp. 216-249.
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This chapter describes recent advances in the development of chiral vanadium and niobium catalysts for enantioselective carbon–carbon bond-forming transformations. The catalyst prepared from a vanadium salt or a niobium salt with a chiral multidentate ligand is a powerful tool for the efficient synthesis of optically enriched compounds such as cyanohydrins, amino alcohols and 1,1′-bi-2-naphthols, which can be readily transformed to biologically active compounds and chiral ligands.
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