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Green Chemistry Series
Supercritical and Other High-pressure Solvent Systems: For Extraction, Reaction and Material Processing
Edited by
Andrew J Hunt;
Andrew J Hunt
Khon Kaen University, Thailand
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Thomas M Attard
Thomas M Attard
University of York, UK
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Hardback ISBN:
978-1-78262-880-4
PDF ISBN:
978-1-78801-354-3
EPUB ISBN:
978-1-78801-518-9
Series:
Green Chemistry
No. of Pages:
678
Published online:
24 Aug 2018
Published in print:
28 Aug 2018
Book Chapter
CHAPTER 8: Selective Hydrogenation in Carbon Dioxide-dissolved Expanded Liquid Phases
By
Haiyang Cheng
;
Haiyang Cheng
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Changchun
130022
P. R. China
[email protected]
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Xiangchun Meng
;
Xiangchun Meng
School of Chemical Engineering, Changchun University of Technology
Changchun
130012
P. R. China
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Fengyu Zhao
;
Fengyu Zhao
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Changchun
130022
P. R. China
[email protected]
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Masahiko Arai
Masahiko Arai
State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences
Changchun
130022
P. R. China
[email protected]Division of Applied Chemistry, Faculty of Engineering, Hokkaido University
Sapporo
060-8628
Japan
[email protected]
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Published:24 Aug 2018
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Series: Green Chemistry
Page range:
221 - 261
Citation
H. Cheng, X. Meng, F. Zhao, and M. Arai, in Supercritical and Other High-pressure Solvent Systems: For Extraction, Reaction and Material Processing, ed. A. J. Hunt and T. M. Attard, The Royal Society of Chemistry, 2018, pp. 221-261.
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The pressurisation of carbon dioxide in organic liquids and water can modify and functionalise their properties and actions as reaction media through interactions of the dissolved carbon dioxide molecules with the solvents, substrates, intermediates, products and/or catalysts. This chapter describes several examples of interesting promotion effects of carbon dioxide on the selective hydrogenation reactions of carbonyl, nitro, nitrile compounds and other substrates.
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