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Enthalpy and Internal Energy: Liquids, Solutions and Vapours
Edited by
Emmerich Wilhelm;
Emmerich Wilhelm
University of Vienna, Austria
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Trevor Letcher
Trevor Letcher
University of KwaZuluNatal, South Africa
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Hardback ISBN:
978-1-78262-711-1
PDF ISBN:
978-1-78801-021-4
EPUB ISBN:
978-1-78801-196-9
No. of Pages:
640
Published online:
08 Sep 2017
Published in print:
12 Sep 2017
Book Chapter
Chapter 19: Excess Enthalpies for Binary Systems Containing Ionic Liquids
By
Jacobo Troncoso
Jacobo Troncoso
Department of Applied Physics, University of Vigo, Campus del Agua
E32004 Ourense
Spain
[email protected]
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Published:08 Sep 2017
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Page range:
505 - 520
Citation
J. Troncoso, in Enthalpy and Internal Energy: Liquids, Solutions and Vapours, ed. E. Wilhelm and T. Letcher, The Royal Society of Chemistry, 2017, ch. 19, pp. 505-520.
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In this chapter, the excess enthalpies for binary mixtures which contain ionic liquids are presented and discussed. It is found that hydrogen bonding systems, i.e. those that contain water or alcohols, show a large range in excess enthalpy values, from highly negative to highly positive. This is especially true for aqueous mixtures. However, systems with other solvents present a much smaller variation in excess enthalpy values.
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