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Catalysis Series
Catalysis with Earth-abundant Elements
Edited by
Stephen Thomas
Stephen Thomas
University of Edinburgh, UK
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Hardback ISBN:
978-1-78801-118-1
PDF ISBN:
978-1-78801-277-5
EPUB ISBN:
978-1-83916-021-9
Special Collection:
2020 ebook collection
Series:
Catalysis Series
No. of Pages:
412
Publication date:
28 Oct 2020
Book Chapter
CHAPTER 13: Recent Advances in Asymmetric Catalysis by Chiral Phosphines
By
Y. Wei
;
Y. Wei
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences
345 Ling-Ling Road
Shanghai 200032
China
mshi@mail.sioc.ac.cn
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M. Shi
M. Shi
State Key Laboratory of Organometallic Chemistry, Center for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences
345 Ling-Ling Road
Shanghai 200032
China
mshi@mail.sioc.ac.cn
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Published:28 Oct 2020
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Special Collection: 2020 ebook collectionSeries: Catalysis Series
Citation
Y. Wei and M. Shi, in Catalysis with Earth-abundant Elements, ed. U. Schneider and S. Thomas, The Royal Society of Chemistry, 2020, pp. 348-403.
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Chiral tertiary phosphines are versatile Lewis base catalysts capable of promoting a wide range of asymmetric reactions. In particular, recently designed chiral phosphines based on the concept of bifunctionality and multifunctionality have been demonstrated to be effective catalysts for various types of asymmetric reactions such as (aza)-MBH reactions, cycloadditions, nucleophilic additions, etc. This chapter summarises the recent advances in this field and highlights selected significant achievements.
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