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New Developments in NMR
Field-cycling NMR Relaxometry: Instrumentation, Model Theories and Applications
Edited by
Rainer Kimmich
Rainer Kimmich
University of Ulm, Germany
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Hardback ISBN:
978-1-78801-154-9
PDF ISBN:
978-1-78801-296-6
EPUB ISBN:
978-1-78801-550-9
Special Collection:
2018 ebook collection
Series:
New Developments in NMR
No. of Pages:
571
Published online:
11 Oct 2018
Published in print:
16 Oct 2018
Book Chapter
Chapter 16: Quantum Molecular Tunnelling Studied by Field-cycling NMR
By
Anthony J. Horsewill
Anthony J. Horsewill
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Published:11 Oct 2018
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Special Collection: 2018 ebook collectionSeries: New Developments in NMR
Page range:
405 - 426
Citation
A. J. Horsewill, in Field-cycling NMR Relaxometry: Instrumentation, Model Theories and Applications, ed. R. Kimmich, The Royal Society of Chemistry, 2018, ch. 16, pp. 405-426.
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An overview is presented of the applications of fast field-cycling NMR to the study of quantum molecular tunnelling. Both incoherent and coherent tunnelling phenomena are examined. Examples presented include concerted double proton transfer in the hydrogen bonds of the benzoic acid dimer and coherent tunnelling of the quantum rotor CH3.
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