Noncovalent Interactions in Catalysis
Noncovalent interactions often provide the spine of biomolecular and material structures, and can therefore play a key role in biological and catalytic processes. Selectivity in chemical reactions, particularly in catalytic processes, is often an orchestral action of various noncovalent interactions occurring in intermediates and transition states. Although the role of hydrogen bonding is well explored in catalysis, the other types of weak interactions, namely cation–π, anion–π, π–π stacking, pseudo-agostic, halogen, chalcogen, pnictogen, tetrel and icosagen bonds, must also be considered. Naturally, the chemo-, regio- or stereoselectivity of a reaction depends on the stability of such noncovalent-interaction-supported species in catalytic systems. Therefore, an in-depth understanding of these weak interactions may be the key to designing new catalytic materials.
Providing an overview of the role of these different types of noncovalent interactions in both homogenous and heterogeneous catalysis, this book is a valuable resource for synthetic chemists who are interested in exploring and further developing noncovalent-interaction-assisted synthesis and catalysis.
Noncovalent Interactions in Catalysis, The Royal Society of Chemistry, 2019.
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CHAPTER 1: Noncovalent Interactions in C–H Bond Functionalizationp1-25ByKamran T. Mahmudov;Kamran T. MahmudovCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Department of Chemistry, Baku State UniversityZ. Xalilov Str. 23Az 1148 BakuAzerbaijan[email protected]Search for other works by this author on:Atash V. Gurbanov;Atash V. GurbanovCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Department of Chemistry, Baku State UniversityZ. Xalilov Str. 23Az 1148 BakuAzerbaijan[email protected]Search for other works by this author on:M. Fátima C. Guedes da Silva;M. Fátima C. Guedes da SilvaCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Search for other works by this author on:Armando J. L. PombeiroArmando J. L. PombeiroCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Search for other works by this author on:
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CHAPTER 2: Importance of C–H Hydrogen Bonding in Asymmetric Catalysisp26-65BySatoru Arimitsu;Satoru ArimitsuDepartment of Chemistry, Biology and Marine Science, University of the RyukyusSenbaru 1, NakagamiNishiharaOkinawa 903-0213Japan[email protected][email protected]Search for other works by this author on:Masahiro HigashiMasahiro HigashiDepartment of Chemistry, Biology and Marine Science, University of the RyukyusSenbaru 1, NakagamiNishiharaOkinawa 903-0213Japan[email protected][email protected]Search for other works by this author on:
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CHAPTER 3: Catalysis by Networks of Cooperative Hydrogen Bondsp66-93ByJosé M. Saá;José M. SaáDepartment de Química, Universitat de les Illes BalearsCrta. de Valldemossa km 7.507122 Palma de MallorcaIlles BalearsSpain[email protected]Search for other works by this author on:Victor J. Lillo;Victor J. LilloDepartment de Química, Universitat de les Illes BalearsCrta. de Valldemossa km 7.507122 Palma de MallorcaIlles BalearsSpain[email protected]Search for other works by this author on:Javier MansillaJavier MansillaDepartment de Química, Universitat de les Illes BalearsCrta. de Valldemossa km 7.507122 Palma de MallorcaIlles BalearsSpain[email protected]Search for other works by this author on:
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CHAPTER 4: Secondary (Agostic Si–H/Electrostatic C–F) Interactions in Alkaline Earth-based Catalystsp94-121ByYann Sarazin;Yann SarazinUniversité de Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 622635000 RennesFrance[email protected][email protected]Search for other works by this author on:Jean-Francois CarpentierJean-Francois CarpentierUniversité de Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 622635000 RennesFrance[email protected][email protected]Search for other works by this author on:
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CHAPTER 5: Anion–π Catalysisp122-136ByRosa M. Gomila;Rosa M. GomilaServeis Cientificotècnics, Universitat de les Illes BalearsCrta. de Valldemossa km 7.507122 Palma de MallorcaIlles BalearsSpainSearch for other works by this author on:Antonio FronteraAntonio FronteraDepartament de Química, Universitat de les Illes BalearsCrta. de Valldemossa km 7.507122 Palma de MallorcaIlles BalearsSpain[email protected]Search for other works by this author on:
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CHAPTER 6: Onium Ion-assisted Organic Reactions Through Cation–π Interactionsp137-152ByShinji YamadaShinji YamadaDepartment of Chemistry, Ochanomizu University2-1-1 OtsukaBunkyo-kuTokyo 112-8610Japan[email protected]Search for other works by this author on:
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CHAPTER 7: The Role of Noncovalent Interactions in the Efficiency of Dendrimers in Catalysisp153-167ByAnne-Marie CaminadeAnne-Marie CaminadeLaboratoire de Chimie de Coordination du CNRS205 Route de Narbonne, BP 4409931077 ToulouseFranceSearch for other works by this author on:
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CHAPTER 8: Noncovalent Interactions in Hydrogenation and Hydroformylationp168-187ByVijay S. Koshti;Vijay S. KoshtiPolymer Science and Engineering Division, CSIR National Chemical LaboratoryDr. Homi Bhabha RoadPune 411008India[email protected]Search for other works by this author on:Samir H. ChikkaliSamir H. ChikkaliPolymer Science and Engineering Division, CSIR National Chemical LaboratoryDr. Homi Bhabha RoadPune 411008India[email protected]Search for other works by this author on:
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CHAPTER 9: Soft Forces in Organic Synthesis by C–N Coupling Reactionsp188-208ByAnima Bose;Anima BoseSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNIBhubaneswar, P.O. Bhimpur-Padanpur, Via Jatni, District KhurdaOdisha 752050India[email protected]Search for other works by this author on:Saikat Maiti;Saikat MaitiSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNIBhubaneswar, P.O. Bhimpur-Padanpur, Via Jatni, District KhurdaOdisha 752050India[email protected]Search for other works by this author on:Prasenjit MalPrasenjit MalSchool of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNIBhubaneswar, P.O. Bhimpur-Padanpur, Via Jatni, District KhurdaOdisha 752050India[email protected]Search for other works by this author on:
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CHAPTER 10: Noncovalent Interactions in the Design of Chiral Brønsted Acid Catalystsp209-231ByNorie MomiyamaNorie MomiyamaInstitute for Molecular Science, SOKENDAI, The Graduate University for Advanced StudiesOkazakiAichi 444-8787Japan[email protected]Search for other works by this author on:
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CHAPTER 11: Noncovalent Interactions in the Nitroaldol (Henry) Reactionp232-252BySusanta Hazra;Susanta HazraCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected][email protected]Search for other works by this author on:Armando J. L. PombeiroArmando J. L. PombeiroCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected][email protected]Search for other works by this author on:
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CHAPTER 12: Noncovalent Interactions in Asymmetric Reactions Catalysed by Chiral Phosphoric Acidsp253-282ByAna Maria Faisca PhillipsAna Maria Faisca PhillipsCoordination Chemistry and Catalysis Group, Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Search for other works by this author on:
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CHAPTER 13: Baeyer–Villiger Oxidation Promoted by Noncovalent Interactionsp283-301ByNuno M. R. Martins;Nuno M. R. MartinsCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected][email protected]Search for other works by this author on:Luísa M. D. R. S. MartinsLuísa M. D. R. S. MartinsCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected][email protected]Search for other works by this author on:
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CHAPTER 14: Noncovalent Interaction-assisted Redox Catalysis in Reductive Dehalogenationp302-323ByStefan S. Kurek;Stefan S. KurekMolecular Electrochemistry Group, Faculty of Chemical Engineering and Technology, Cracow University of Technologyul. Warszawska 2431-155 KrakówPoland[email protected][email protected]Search for other works by this author on:Piotr P. RomańczykPiotr P. RomańczykMolecular Electrochemistry Group, Faculty of Chemical Engineering and Technology, Cracow University of Technologyul. Warszawska 2431-155 KrakówPoland[email protected][email protected]Search for other works by this author on:
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CHAPTER 15: Noncovalent Immobilization of Catalysts on Electrode Surfacesp324-349ByKatie J. Johnson;Katie J. JohnsonDepartment of Chemistry, University of Kansas1567 Irving Hill RoadLawrenceKS 66045USA[email protected]Search for other works by this author on:Keaton V. Prather;Keaton V. PratherDepartment of Chemistry, University of Kansas1567 Irving Hill RoadLawrenceKS 66045USA[email protected]Search for other works by this author on:James D. BlakemoreJames D. BlakemoreDepartment of Chemistry, University of Kansas1567 Irving Hill RoadLawrenceKS 66045USA[email protected]Search for other works by this author on:
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CHAPTER 16: Noncovalent Interactions in Ionic Liquidsp350-376ByPatricia A. HuntPatricia A. HuntSearch for other works by this author on:
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CHAPTER 17: Ionic Liquid Effect in Catalysed Multicomponent Reactionsp377-392ByBrenno A. D. Neto;Brenno A. D. NetoLaboratory of Medicinal and Technological Chemistry, University of Brasilia (IQ-UnB)Campus Universitario Darcy Ribeiro, P.O. Box 4478CEP 70904970Brasilia, DFBrazil[email protected]Search for other works by this author on:Haline G. O. Alvim;Haline G. O. AlvimLaboratory of Medicinal and Technological Chemistry, University of Brasilia (IQ-UnB)Campus Universitario Darcy Ribeiro, P.O. Box 4478CEP 70904970Brasilia, DFBrazil[email protected]Search for other works by this author on:Alexandre A. M. LapisAlexandre A. M. LapisUniversidade Federal da Fronteira SulChapecóSCBrazilSearch for other works by this author on:
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CHAPTER 18: Noncovalent Interactions in Olefin Polymerization Catalysis Promoted by Transition Metalsp393-414ByMassimo Christian D'Alterio;Massimo Christian D'AlterioDipartimento di Scienze Chimiche, Università di Napoli Federico IIVia Cintia80126 NaplesItaly[email protected]Search for other works by this author on:Claudio de Rosa;Claudio de RosaDipartimento di Scienze Chimiche, Università di Napoli Federico IIVia Cintia80126 NaplesItaly[email protected]Search for other works by this author on:Giovanni TalaricoGiovanni TalaricoDipartimento di Scienze Chimiche, Università di Napoli Federico IIVia Cintia80126 NaplesItaly[email protected]Search for other works by this author on:
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CHAPTER 19: Influence of Noncovalent Interactions in Catalytic Ring-opening Polymerization Processesp415-439ByMarta E. G. Mosquera;Marta E. G. MosqueraDepartment of Organic and Inorganic Chemistry, Faculty of Pharmacy, University of AlcaláUniversity Campus28805 Alcalá de HenaresMadridSpain[email protected]Search for other works by this author on:Miguel Palenzuela;Miguel PalenzuelaDepartment of Organic and Inorganic Chemistry, Faculty of Pharmacy, University of AlcaláUniversity Campus28805 Alcalá de HenaresMadridSpain[email protected]Search for other works by this author on:María Fernández-MillánMaría Fernández-MillánDepartment of Organic and Inorganic Chemistry, Faculty of Pharmacy, University of AlcaláUniversity Campus28805 Alcalá de HenaresMadridSpain[email protected]Search for other works by this author on:
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CHAPTER 20: Cavity Effects in Metal–Organic Frameworksp440-454ByVíctor L. Rechac;Víctor L. RechacInstituto de Tecnología Química UPV-CSIC, Universitat Politècnica de València, Consejo Superior de Investigaciones CientíficasAvda. de los Naranjos s/n46022 ValenciaSpain[email protected]Search for other works by this author on:Encarnación Peris Sanchis;Encarnación Peris SanchisInstituto de Tecnología Química UPV-CSIC, Universitat Politècnica de València, Consejo Superior de Investigaciones CientíficasAvda. de los Naranjos s/n46022 ValenciaSpain[email protected]Search for other works by this author on:Francesc X. Llabrés i XamenaFrancesc X. Llabrés i XamenaInstituto de Tecnología Química UPV-CSIC, Universitat Politècnica de València, Consejo Superior de Investigaciones CientíficasAvda. de los Naranjos s/n46022 ValenciaSpain[email protected]Search for other works by this author on:
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CHAPTER 21: Application of Metal–Organic Frameworks in CO2 Capture and Conversionp455-478ByCheng-Yong SuCheng-Yong SuSearch for other works by this author on:
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CHAPTER 22: Hybrids of Metal–Organic Frameworks as Organized Supramolecular Nano-reactorsp479-502ByLeonid M. Kustov;Leonid M. KustovN. D. Zelinsky Institute of Organic Chemistry, Russian Academy of SciencesLeninsky Prospect 47Moscow 119991RussiaNational University of Science and Technology “MISiS”Leninsky Prospect 4Moscow 119991RussiaChemistry Department, Moscow State UniversityLeninskie Gory 1, Bldg. 3Moscow 119991Russia[email protected]Search for other works by this author on:Vera I. IsaevaVera I. IsaevaN. D. Zelinsky Institute of Organic Chemistry, Russian Academy of SciencesLeninsky Prospect 47Moscow 119991RussiaNational University of Science and Technology “MISiS”Leninsky Prospect 4Moscow 119991RussiaSearch for other works by this author on:
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CHAPTER 23: The Nature of Hydrogen Bonding in Adsorbed CO2 and H2O on Solid Amines in CO2 Capturep503-526ByY. Zhai;Y. ZhaiDepartment of Polymer Science, University of Akron170 University AvenueAkronOH 44325USA[email protected]Search for other works by this author on:S. Wang;S. WangDepartment of Polymer Science, University of Akron170 University AvenueAkronOH 44325USA[email protected]Search for other works by this author on:Steven S. C. ChuangSteven S. C. ChuangDepartment of Polymer Science, University of Akron170 University AvenueAkronOH 44325USA[email protected]Search for other works by this author on:
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CHAPTER 24: Noncovalent Interactions of Biogenic Impurities with Transition Metal Catalyst Surfacesp527-547ByMadhulika Gupta;Madhulika GuptaRenewable Energy and Chemicals Laboratory, Department of Chemical Engineering, Indian Institute of Technology DelhiHauz KhasNew Delhi 110016India[email protected]Department of Chemistry, Indian Institute of Technology DelhiHauz KhasNew Delhi 110016IndiaSearch for other works by this author on:Tuhin S. Khan;Tuhin S. KhanRenewable Energy and Chemicals Laboratory, Department of Chemical Engineering, Indian Institute of Technology DelhiHauz KhasNew Delhi 110016India[email protected]Search for other works by this author on:Manish Agarwal;Manish AgarwalComputer Services Centre, Indian Institute of Technology DelhiHauz KhasNew Delhi 110016India[email protected]Search for other works by this author on:M. Ali HaiderM. Ali HaiderRenewable Energy and Chemicals Laboratory, Department of Chemical Engineering, Indian Institute of Technology DelhiHauz KhasNew Delhi 110016India[email protected]Search for other works by this author on:
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CHAPTER 25: Mechanochemical Activation and Catalysisp548-563ByMaximilian N. Kopylovich;Maximilian N. KopylovichCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Search for other works by this author on:Ana P. C. Ribeiro;Ana P. C. RibeiroCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Search for other works by this author on:Elisabete C. B. A. AlegriaElisabete C. B. A. AlegriaCentro de Química Estrutural, Instituto Superior Técnico, Universidade de LisboaAv. Rovisco Pais1049-001 LisbonPortugal[email protected]Departamento de Engenharia Química, Instituto Superior de Engenharia de Lisboa, Instituto Politécnico de LisboaR. Conselheiro Emídio Navarro1959-007 LisbonPortugalSearch for other works by this author on:
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CHAPTER 26: Role of Ion Pairing in the Mechanisms of Au(i)-catalysed Reactions: Theory and Experimentp564-578ByDaniele Zuccaccia;Daniele ZuccacciaDipartimento di Scienze Agroalimentari, Ambientali e Animali, Sezione di Chimica, Università di UdineVia Cotonificio 10833100 UdineItaly[email protected]Search for other works by this author on:Paola Belanzoni;Paola BelanzoniDipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di PerugiaVia Elce di Sotto 806123 PerugiaItalyIstituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), c/o Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di PerugiaVia Elce di Sotto 806123 PerugiaItalyConsortium for Computational Molecular and Materials Sciences (CMS)2Via Elce di Sotto 806123 PerugiaItalySearch for other works by this author on:Leonardo Belpassi;Leonardo BelpassiIstituto di Scienze e Tecnologie Molecolari del CNR (CNR-ISTM), c/o Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di PerugiaVia Elce di Sotto 806123 PerugiaItalyConsortium for Computational Molecular and Materials Sciences (CMS)2Via Elce di Sotto 806123 PerugiaItalySearch for other works by this author on:Gianluca Ciancaleoni;Gianluca CiancaleoniDipartimento di Chimica e Chimica Industriale (DCCI), Università di PisaVia Giuseppe Moruzzi 1356124 PisaItalyCIRCC – Consorzio Interuniversitario per le Reattività Chimiche e la CatalisiVia Celso Ulpiani 2770126 BariItalySearch for other works by this author on:Alessandro Del ZottoAlessandro Del ZottoDipartimento di Scienze Agroalimentari, Ambientali e Animali, Sezione di Chimica, Università di UdineVia Cotonificio 10833100 UdineItaly[email protected]Search for other works by this author on:
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CHAPTER 27: Noncovalent Interactions in Key Metal-centred Catalytic Intermediates: Structure–Electronic Relationshipp579-607ByMustapha Hamdaoui;Mustapha HamdaouiUniversité de Strasbourg et Centre National de la Recherche Scientifique, Institut de Chimie de Strasbourg UMR 71774 rue Blaise Pascal67000 StrasbourgFrance[email protected]Search for other works by this author on:Jean-Pierre DjukicJean-Pierre DjukicUniversité de Strasbourg et Centre National de la Recherche Scientifique, Institut de Chimie de Strasbourg UMR 71774 rue Blaise Pascal67000 StrasbourgFrance[email protected]Search for other works by this author on:
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CHAPTER 28: Noncovalent Interactions in Biocatalysis – A Theoretical Perspectivep608-627ByGunasekaran Velmurugan;Gunasekaran VelmuruganTheoretical and Computational Chemistry Laboratory, School of Chemistry, Bharathidasan UniversityTiruchirappalli 620 024Tamil NaduIndia[email protected]Search for other works by this author on:Rajadurai Vijay Solomon;Rajadurai Vijay SolomonDepartment of Chemistry, Madras Christian College (Autonomous)East TambaramChennai 600 059Tamil NaduIndiaSearch for other works by this author on:Dhurairajan Senthilnathan;Dhurairajan SenthilnathanCentre for Computational Chemistry, CRD, PRIST UniversityVallamThanjavur 613 403Tamil NaduIndiaSearch for other works by this author on:Ponnambalam VenuvanalingamPonnambalam VenuvanalingamTheoretical and Computational Chemistry Laboratory, School of Chemistry, Bharathidasan UniversityTiruchirappalli 620 024Tamil NaduIndia[email protected]Search for other works by this author on:
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CHAPTER 29: Analysis of Reactivity from the Noncovalent Interactions Perspectivep628-643ByRoberto A. Boto;Roberto A. BotoSorbonne Universités, UPMC Université de Paris 06, CNRS, Laboratoire de Chimie Théorique (LCT)4 Place Jussieu75005 ParisFrance[email protected]CICECO: Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, Complexo de Laboratórios TecnológicosCampus Universitário de Santiago3810-193 AveiroPortugalSearch for other works by this author on:Tatiana Woller;Tatiana WollerSorbonne Universités, UPMC Université de Paris 06, CNRS, Laboratoire de Chimie Théorique (LCT)4 Place Jussieu75005 ParisFrance[email protected]Eenheid Algemene Chemie (ALGC), Vrije Universiteit Brussel (VUB)Pleinlaan 21050 BrusselsBelgiumSearch for other works by this author on:Julia Contreras-García;Julia Contreras-GarcíaSorbonne Universités, UPMC Université de Paris 06, CNRS, Laboratoire de Chimie Théorique (LCT)4 Place Jussieu75005 ParisFrance[email protected]Search for other works by this author on:Israel FernándezIsrael FernándezDepartamento de Química Orgánica I y Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias Químicas, Universidad Complutense de Madrid28040 MadridSpain[email protected]Search for other works by this author on:
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