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New Developments in NMR
Long-lived Nuclear Spin Order: Theory and Applications
Edited by
Giuseppe Pileio
Giuseppe Pileio
University of Southampton, UK
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Hardback ISBN:
978-1-78801-568-4
PDF ISBN:
978-1-78801-997-2
EPUB ISBN:
978-1-78801-998-9
Special Collection:
2020 ebook collection
Series:
New Developments in NMR
No. of Pages:
442
Published online:
07 Apr 2020
Published in print:
15 Apr 2020
Book Chapter
Chapter 20: Long-lived Coherences
By
A. Sadet
;
A. Sadet
Research Institute of the University of Bucharest (ICUB)
36-46 B-dul M. Kogalniceanu
RO-050107 Bucharest
Romania
[email protected]Extreme Light Infrastructure – Nuclear Physics ELI-NP, “Horia Hulubei” National Institute for Physics and Nuclear Engineering IFIN-HH
30 Reactorului Street
RO-077125 Bucharest-Magurele
Romania
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R. Sarkar
;
R. Sarkar
Bavarian NMR Center (BNMRZ)
Ernst-Otto-Fischer Str. 2
Garching
Germany
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F. Teleanu
;
F. Teleanu
Research Institute of the University of Bucharest (ICUB)
36-46 B-dul M. Kogalniceanu
RO-050107 Bucharest
Romania
[email protected]
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G. Bodenhausen
;
G. Bodenhausen
Laboratoire des biomolécules, LBM, Département de chimie, École normale supérieure, PSL University, Sorbonne Université, CNRS
75005 Paris
France
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P. R. Vasos
P. R. Vasos
Research Institute of the University of Bucharest (ICUB)
36-46 B-dul M. Kogalniceanu
RO-050107 Bucharest
Romania
[email protected]Extreme Light Infrastructure – Nuclear Physics ELI-NP, “Horia Hulubei” National Institute for Physics and Nuclear Engineering IFIN-HH
30 Reactorului Street
RO-077125 Bucharest-Magurele
Romania
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Published:07 Apr 2020
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Special Collection: 2020 ebook collectionSeries: New Developments in NMR
Page range:
371 - 388
Citation
A. Sadet, R. Sarkar, F. Teleanu, G. Bodenhausen, and P. R. Vasos, in Long-lived Nuclear Spin Order: Theory and Applications, ed. G. Pileio, The Royal Society of Chemistry, 2020, ch. 20, pp. 371-388.
Download citation file:
Coherent superpositions between nuclear singlet and triplet spin states of pairs of J-coupled nuclei in high magnetic fields can be excited and sustained by oscillating radio-frequency (rf) radiation. The relaxation time constants of these ‘long-lived coherences’ can be up to nine times longer than those of allowed single-quantum coherences. We detail herein the development and early applications of long-lived coherences.
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