Nitroxides
Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.
Nitroxides, The Royal Society of Chemistry, 2021.
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Table of contents
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A Brief History and Outlook of Nitroxidesp1-6
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Chapter 2: General Approaches to Synthesis of Nitroxidesp7-70ByIgor A. Kirilyuk;Igor A. KirilyukN.N.Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RASPr. Lavrentieva 9Novosibirsk630090Russian Federation[email protected]Search for other works by this author on:Dmitrii G. MazhukinDmitrii G. MazhukinN.N.Vorozhtsov Novosibirsk Institute of Organic Chemistry SB RASPr. Lavrentieva 9Novosibirsk630090Russian Federation[email protected]Search for other works by this author on:
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Chapter 3: The Application of Nitroxides in Organic Synthesisp71-146ByAlex. M. SzpilmanAlex. M. SzpilmanSearch for other works by this author on:
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Chapter 4: Spin Probes and Imaging Using Nitroxidesp147-186ByValery V. KhramtsovValery V. KhramtsovIn Vivo Multifunctional Magnetic Resonance center, Robert C. Byrd Health Science Center, West Virginia UniversityMorgantownWV 26506USA[email protected]Department of Biochemistry, West Virginia University School of MedicineMorgantownWV 26506USASearch for other works by this author on:
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Chapter 5: Nitroxides in Battery-related Applicationsp187-212ByB. Ernould;B. ErnouldCatholic University of Louvain (UCLouvain), Institute of Condensed Matter and Nanosciences (IMCN)Place L. Pasteur 1, 1348Louvain-la-NeuveBelgium[email protected]Search for other works by this author on:J.-F. GohyJ.-F. GohyCatholic University of Louvain (UCLouvain), Institute of Condensed Matter and Nanosciences (IMCN)Place L. Pasteur 1, 1348Louvain-la-NeuveBelgium[email protected]Search for other works by this author on:
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Chapter 6: Computational Tools for Nitroxide Designp213-262ByNicholas S. Hill;Nicholas S. HillARC Centre of Excellence for Electromaterials Science, Research School of ChemistryAustralian National UniversityCanberra ACT 2601Australia[email protected]Search for other works by this author on:Benjamin B. Noble;Benjamin B. NobleARC Centre of Excellence for Electromaterials Science, Research School of ChemistryAustralian National UniversityCanberra ACT 2601Australia[email protected]Search for other works by this author on:Fergus J. M. Rogers;Fergus J. M. RogersARC Centre of Excellence for Electromaterials Science, Research School of ChemistryAustralian National UniversityCanberra ACT 2601Australia[email protected]Search for other works by this author on:Alfred K. K. Fung;Alfred K. K. FungARC Centre of Excellence for Electromaterials Science, Research School of ChemistryAustralian National UniversityCanberra ACT 2601Australia[email protected]Search for other works by this author on:Michelle L. CooteMichelle L. CooteARC Centre of Excellence for Electromaterials Science, Research School of ChemistryAustralian National UniversityCanberra ACT 2601Australia[email protected]Search for other works by this author on:
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Chapter 7: Nitroxide-mediated Polymerizationp263-316ByAlexandre Simula;Alexandre SimulaPOLYMAT and Kimika Aplikatua Saila, University of the Basque Country UPV/EHU, Joxe Mari Korta ZentroaTolosa Hiribidea 7220018Donostia/San SebastiánSpain[email protected]Search for other works by this author on:Nicholas Ballard;Nicholas BallardPOLYMAT and Kimika Aplikatua Saila, University of the Basque Country UPV/EHU, Joxe Mari Korta ZentroaTolosa Hiribidea 7220018Donostia/San SebastiánSpain[email protected]IKERBASQUE, Basque Foundation for Science48011 BilbaoSpainSearch for other works by this author on:José M. AsuaJosé M. AsuaPOLYMAT and Kimika Aplikatua Saila, University of the Basque Country UPV/EHU, Joxe Mari Korta ZentroaTolosa Hiribidea 7220018Donostia/San SebastiánSpain[email protected]Search for other works by this author on:
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Chapter 8: Nitroxides in Supramolecular Chemistryp317-358ByElisabetta Mezzina;Elisabetta MezzinaAlma mater Studiorum – University of Bologna, Department of Chemistry “Giacomo Ciamician”Via San Giacomo 11BolognaI-40136Italy[email protected][email protected]Search for other works by this author on:Marco LucariniMarco LucariniAlma mater Studiorum – University of Bologna, Department of Chemistry “Giacomo Ciamician”Via San Giacomo 11BolognaI-40136Italy[email protected][email protected]Search for other works by this author on:
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Chapter 9: Magnetism of Nitroxidesp359-391ByAndrzej RajcaAndrzej RajcaSearch for other works by this author on:
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Chapter 10: Applications of Nitroxide Spin Labels to Structural Biologyp392-419ByC. S. Klug;C. S. KlugMedical College of Wisconsin, Department of Biophysics8701 Watertown Plank RoadMilwaukeeWI 53226USA[email protected]Search for other works by this author on:M. T. Lerch;M. T. LerchMedical College of Wisconsin, Department of Biophysics8701 Watertown Plank RoadMilwaukeeWI 53226USA[email protected]Search for other works by this author on:J. B. FeixJ. B. FeixMedical College of Wisconsin, Department of Biophysics8701 Watertown Plank RoadMilwaukeeWI 53226USA[email protected]Search for other works by this author on:
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Chapter 11: Nitroxides in Liquid Crystalsp420-448ByRui Tamura;Rui TamuraKyoto University, Graduate School of Human and Environmental StudiesKyoto 606-8501Japan[email protected]Search for other works by this author on:Yoshiaki Uchida;Yoshiaki UchidaOsaka University, Graduate School of Engineering ScienceToyonaka, Osaka 560-8531JapanSearch for other works by this author on:Kota NaguraKota NaguraKyoto University, Graduate School of Human and Environmental StudiesKyoto 606-8501Japan[email protected]Search for other works by this author on:
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Chapter 12: Nitroxide Intervention in Oxidative and Free Radical Damage in Biology and Diseasep449-481BySteven E. Bottle;Steven E. BottleSchool of Chemistry and Physics, Queensland University of Technology, (QUT)Australia[email protected]Search for other works by this author on:Grace Eng;Grace EngSchool of Chemistry and Physics, Queensland University of Technology, (QUT)Australia[email protected]Search for other works by this author on:Paul Witting;Paul WittingDiscipline of Pathology, School of Medical Sciences, Faculty of Medicine and Health, University of SydneyAustraliaSearch for other works by this author on:Belal ChamiBelal ChamiDiscipline of Pathology, School of Medical Sciences, Faculty of Medicine and Health, University of SydneyAustraliaSearch for other works by this author on:
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Chapter 13: Spin Trappingp482-518ByJ. Zielonka;J. ZielonkaDepartment of Biophysics, Medical College of Wisconsin8701 Watertown Plank RoadMilwaukeeWI 53226USA[email protected]Search for other works by this author on:M. Hardy;M. HardyAix Marseille UnivCNRS, ICR, UMR 7273Marseille 13013FranceSearch for other works by this author on:B. KalyanaramanB. KalyanaramanDepartment of Biophysics, Medical College of Wisconsin8701 Watertown Plank RoadMilwaukeeWI 53226USA[email protected]Search for other works by this author on:
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Chapter 14: Biological Applications of Nitroxide Stable Free Radicalsp519-550BySarwat Naz;Sarwat NazRadiation Biology Branch, Center for Cancer Research, National Cancer Institute9000 Rockville PikeBethesdaMaryland 20892USA[email protected]Search for other works by this author on:John A. Cook;John A. CookRadiation Biology Branch, Center for Cancer Research, National Cancer Institute9000 Rockville PikeBethesdaMaryland 20892USA[email protected]Search for other works by this author on:Murali C. Krishna;Murali C. KrishnaRadiation Biology Branch, Center for Cancer Research, National Cancer Institute9000 Rockville PikeBethesdaMaryland 20892USA[email protected]Search for other works by this author on:James B. MitchellJames B. MitchellRadiation Biology Branch, Center for Cancer Research, National Cancer Institute9000 Rockville PikeBethesdaMaryland 20892USA[email protected]Search for other works by this author on:
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Chapter 15: Introduction to Electron Paramagnetic Resonance (EPR) of Nitroxidesp551-579ByGareth R. Eaton;Gareth R. EatonUniversity of Denver, Department of Chemistry and Biochemistry2101 E. Wesley AveDenverColorado 80210USA[email protected]Search for other works by this author on:Sandra S. EatonSandra S. EatonUniversity of Denver, Department of Chemistry and Biochemistry2101 E. Wesley AveDenverColorado 80210USA[email protected]Search for other works by this author on:
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